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Spontaneous Combustion of Coal                                    351
































           Figure 21.3 Predicted versus experimental minimum self-heating temperatures (SHTs) of
           bituminous coals.

                  160

                  140

                  120
                 Temperature (°C)  100



                   80
                   60     16°C/h  8°C/h    4°C/h                2°C/h

                   40
                     0     2     4     6     8    10    12    14   16    18
                                            Time (hours)
                           QLD1  QLD2  QLD3  QLD4  QLD5  NSW1  NSW2
           Figure 21.4 Temperature rise Vs oxidation time for Australian coals. [3]

           In general,  dT  decreases with the rank of coal and has a corresponding higher value of
                    dt

           SHT. E (K cal/mol) and A  Kelvin  also appear to increase with the rank of coal.
                                    s
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