Page 290 - Advances in Eco-Fuels for a Sustainable Environment
P. 290

252
                                               [81]
                    Ref.
                                                        [81]
                                                                 [77]
                    (%)
                    yield
                    Max.
                                                        94.6
                                               99.7
                                                                 42
                                                                   speed¼500rpm.
                                                                 (20wt%)
                                                                     (ml/g)
                                                                 pumice
                                           2mL
                                                                     biomass¼12:1
                                                                   Mixing
                                                    50μL
                                                            H 2 SO 4 :50μL
                                           chloroform:
                    conditions
                                                                 impregnated
                                                        200mg
                                               200mg
                                                      t¼1h
                                                               t¼1h
                                                                   t¼3h,
                                                    H 2 SO 4:
                                             t¼2h
                                                 2mL
                                                          1mL
                                               biomass:
                                                        biomass:
                                                                     to
                    Operating
                                                               T¼100°C,
                                                      T¼100°C,
                                           Cosolvent
                                                 Methanol:
                                                                   T¼80°C,
                                             T¼95°C,
                                                                     Methanol
                                                                 Catalyst:
                                                          Ethanol:
                                                    Catalyst
                                                            Catalyst
                                               Wet
                                                        Wet
                                               (moisture
                       B-3  [85]  99.5  pressure  high Pre-treatment:  homogenization  (N435)  435 Novozym  Catalyst:  ratio¼0.32:1  mass  oil  to  N435  (ml/g)  1 ratio¼4.6:  oil  to Methanol  (ml/g) ratio¼7.1:1  oil  to t-butanol  t¼56h T¼40°C,  [84] 85.7 1.7  1mL Methanol:  (DI  0.3mL  HCl: Catalyst moisture  Advances in Eco-Fuels for a Su
                       gaditana       gaditana  80%  salina      powder)
                    strains  biomass)    saturation:   1%)       (dry  sp.
                    Microalgae  Nannochlo-ropsis  dry  (25%  Nannochlo-ropsis  water  content)  Nannochlo-ropsis  76.5  content:  Chlorella
                Continued
                9.6      trans(esterification)  trans(esterification)  trans(esterification)  trans(esterification)
                Table  Process  situ  In  situ  In  situ  In     situ  In
   285   286   287   288   289   290   291   292   293   294   295