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Ref. 72 73 32 80 87 90 92
LOD (mg/l) 1–5 0.4–0.8 1.0 1.0 0.5–2.0 2.8–4.4 25 pg/mg
m m m
Detection APCI-Q, SIM ESI-Q, SIM ESI-qTOF/SIM ESI-QQQ, MRM ESI-QQQ, MRM ESI-QQQ, MRM ESI-QQQ, MRM
Column, Elution Conditions C18, ACN-HCOONH 4 isocr. CN, ACN-CH 3 COONH 4 isocr. C18, ACN-CH 3 COONH 4 isocr. C18, ACN-CH 3 COONH 4 isocr. C18, ACN-H 2 O gradient C8, MeOH/ACN-CH 3 COONH 4 isocr. C18, ACN-CH 3 COONH 4 gradient A = amphetamine, MA = methamphetamine, MDMA = methylenedioxymethamphetamine,
LC/MS Methods Used for Amphetamines and Cocaine
Isolation SPE SPME l/l SPE SPE SPE SPE quadrupole, qTOF = quadrupole/time-of-flight, SIM = selected ion monitoring, MRM = multiple reaction monitoring, ACN = acetonitrile.
Sample Plasma Urine Plasma Saliva Urine Plasma Hair
Drug 14 Amphetamines and related compounds A, MA, MDMA, MDEA, MDA A, MA, MDMA, MDEA, MDA, E Cocaine, BZE, cocaethylene © 2004 by CRC Press LLC
Table 2.2 MDMA, MDEA, MDA Cocaine, BZE, EME Cocaine, BZE, EME, ECG Notes: