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344                                                  11  Air Dispersion

              Consider an instantaneous short-term release of air pollutant from a stack, where
            the mass of air pollutant released is mðkgÞ. Integrating Eq. (11.57) with the
            boundary conditions

                         C ! 0ast !1; x; y; z   0
                         C ! 0ast ! 0; x; y; z [ 0
                          Z 1 1  Z 1
                                 Cdxdydz ¼ m  ðconservation of massÞ
                            Z
                          0  1  1
            leads to

                                              "                 !#
                                   m             1   x 2  y 2  z 2
                 Cx; y; z; tÞ ¼            exp         þ    þ           ð11:58Þ
                   ð
                                 3        1      4t D    D    D
                                 2
                             ð 4ptÞ D x D y D z  2    x   y    z
              Similar to Eq. (11.31), we define
                                    2
                                   r ¼ 2D i t  i ¼ x; y; z              ð11:59Þ
                                    i
            and Eq. (11.58) can be rewritten in another form as
                                             "     #   "        2  #

                          m            x 2       y 2      ð z   HÞ

                 C ¼             exp      exp       exp           :     ð11:60Þ
                         3=2          2r 2      2r 2        2r 2
                     ð 2pÞ  r x r y r z  x        y           z
              When not available, the x-direction dispersion coefficient can be approximate
            using r x   r y because they both are for horizontal directions.
              The Gaussian puff model is useful in safety analysis of accidental release of air
            pollutants and other chemicals rather than a continuous release of air pollutants.
            Readers are referred to the literature for in-depth understanding of these topics.
              Corresponding computer programs have been developed for different models
            and they are widely available at government agencies and consulting firms, case by
            case. However, users of any air dispersion models must be advised that they are for
            estimates with differences from actual observations as a result of inversion aloft,
            short-term fluctuations, inversion breakup fumigation, etc. Advanced dispersion
            models aiming at these additional topics are available in literature and readers are
            suggested to explore them as needed.




            11.5 Practice Problems

            1. An air parcel temperature is 300 K and the surrounding atmosphere temperature
              is 280 K, what is the acceleration of this air parcel at this location? Assume air
              pressure p = 1 atm.
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