Page 430 - Air pollution and greenhouse gases from basic concepts to engineering applications for air emission control
P. 430

410                                                   13 Nanoaerosol

              Equation (13.28) becomes

                                                    "         #
                                                              2
                                    2 v cr   4 v cr    4  v cr
                          g ¼ erf p  ffiffiffi         exp                    ð13:30Þ
                           ad
                                     p v im  p v im    p v im
              For the ease of presentation, we define an interim term
                                             2 v cr
                                        z ¼ p ffiffiffi                       ð13:31Þ
                                              p v im

              The equation for adhesion energy can be simply presented as
                                              2z       2
                                 g ¼ erf zðÞ   p exp  z                 ð13:32Þ
                                  ad
                                               ffiffiffi
                                               p
              For the ease of calculation without software, the error function can be approx-
            imated with

                                                  1
                           erf zðÞ   1                                  ð13:33Þ
                                                 2     3     4 4
                                      ð 1 þ a 1 z þ a 2 z þ a 3 z þ a 4 z Þ
            where a 1 = 0.278393, a 2 = 0.230389, a 3 = 0.000972, and a 4 = 0.078108. The
                                −4
            maximum error is 5 × 10  (Fortran 77 manual).



            13.4.5 Adhesion Energy

            Several models of adhesion energy (E ad ) were developed before and they were
            summarized by Givehchi and Tan [16]. As guidance, we will introduce only two of
            them, the JKR model [24] and the DMT model [11]. These two models complement
            each other because they represent two extremes in the Tabor parameter spectrum.
            JKR model is applicable to soft material, large radius, compliant spheres, and large
            adhesion energy and DMT model is for hard material, small radius with low
            adhesion energy [33]. The effectiveness of the DMT model has been proven for
            smaller and stiffer contact solids [44]. However, the main defect in this theory is
            that it neglects deformations outside the contact area [33].
              Consider a nanoparticle deformed on the solid surface in Fig. 13.6. The adhesion
            energy between the particles and the surface of the filter material can be mathe-
            matically calculated based on consideration of elastic or plastic impaction.

                                        E ad ¼ Dcpa 2                   ð13:34Þ
   425   426   427   428   429   430   431   432   433   434   435