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Thermohydromechanical behaviour of soils and soil structure interfaces  229


                   volumetric behaviour of coarse-grained soils under nonisothermal conditions. Despite
                   the inherently different nature of the processes that govern the behaviour of soils
                   depending on their mineralogy, the following common underlying aspects can be
                   highlighted for both fine- and coarse-grained soils.
                      If the soil particles were fixed, the thermal expansion of each soil constituent
                   would produce a global dilation of the solid skeleton, with an associated increase in
                   the pore size and the interparticle distance (François, 2008). However, soil particles are
                   not fixed. Therefore, particle rearrangement can occur with an increase in temperature
                   and is associated with the phenomenon of thermal collapse. In particular, while the
                   volumetric behaviour of NC soils appears to be driven by particle rearrangement
                   (whose effect is predominant with respect to the thermoelastic expansion of the soil
                   particles), the behaviour of OC soils appears to be dominated by the thermoelastic
                   expansion of the soil particles (with a minimum influence of particle rearrangement)
                   (Di Donna and Laloui, 2013). In this context, the thermoplastic deformation of
                   soils upon heating is associated with an unstable configuration of the solid particles,
                   while the thermoelastic deformation of soils is associated with a particularly
                   stable configuration of the particles. The presence of unstable voids is considered to
                   facilitate the occurrence of thermal collapse in coarse-grained soils (Sitharam, 2003). In
                   any case, the significance of the thermal collapse phenomenon appears to depend on
                   the magnitude of the pores size (i.e. void ratio) prior to heating, because greater pores
                   represent a higher potential for collapse (Di Donna and Laloui, 2015). Further consid-
                   erations specifically apply to fine- and coarse-grained soils.
                      In fine-grained soils, the magnitude of the thermal collapse phenomenon appears
                   to be proportional to the plasticity index, I p , that is an indicator of the significance of
                   chemical interactions in fine-grained soils (Demars and Charles, 1982; Abuel-Naga
                   et al., 2006; Di Donna and Laloui, 2015). Data available in the literature on this aspect
                   are collected in Fig. 5.16 and Table 5.1. Despite the scatter between the data, which
                   prevents from an unequivocal relation between the plasticity index and the volumetric
                   strain of the soil per unit temperature change, a more significant volumetric deforma-
                   tion per unit temperature change characterises soils with a higher plasticity index, I p .
                   In other words, the intensity of the irreversible part of deformation appears to be inde-
                   pendent of the stress state in the NC range for fine-grained soils, but dependent on
                   soil type and plasticity (Plum and Esrig, 1969).
                      Other phenomena contributing to the thermal collapse phenomenon in fine-
                   grained soils appear to be (1) the degradation of the adsorbed water layer with an
                   increase in temperature that tends to form larger voids (Fleureau, 1979; Pusch, 1986),
                   (2) the modification of the contact forces network due to the differences between the
                   rigidities and the thermal expansion of the different minerals involved (Kingery et al.,
                   1976) and (3) and the changes in the equilibrium between the Van der Waals
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