Page 105 - Applied Process Design For Chemical And Petrochemical Plants Volume II
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94                        Applied Process Design for Chemical and Petrochemical Plants

         Drickamer and Bradford curve,  E,  = 46%                1. Assume or set condenser liquid product temperature,
         O’Connell curve,          E,  = 53.8%                     tD.
                                                                 2. Calculate  condensing pressure,  with  tD  as bubble
         In this case, recommend using:                            point  (if subcooling exists, and tD  is below bubble
                                                                   point, use bubble point temperature for pressure cal-
         E,  e (46 + 53.8)/2 = 49.6%                               culation only).
                                                                 3. Vi = L + D
         Actual trays in column:
                                                                                      +
                                                                    HlVl= [L h~ + D h~]                     (8-184)
         Nact = 20/0.496 = 40.3 trays
                                                                                                             -
           From tray-by-tray calculations, feed tray is  10/0.496 =                                        (8 185)
         20.1 trays from bottom, use 20.
           Generally, practice would be to select a column allowing
         a few extra trays, making column total trays = 45.

                      No.
         Rectifying trays  = 22
         Feed         =1                                         4. Calculate tl and xi by  dew point on vapor VI. Then
         Stripping    =22
                        45                                         determine HI, referring to top tray as number one in
                                                                    this case.
           Feed nozzles should be located on trays Nos. 21,23, and   where  HI= total vapor enthalpy above reference datum
         25 counting up from the bottom tray as No. 1.                        for sum of all contributing percentages of
                                                                              individual components, i, in stream, Btu/lb,
         Heat Balan-Mjacent    Key sgstems with Sharp                         or Btu/mol
         Separations, Constant Molal Overflow                            hD = total liquid enthalpy above reference datum
                                                                              for sum of all contributing percentages of
         Total Conhser Duty                                                   individual components, i, in product stream.
                                                                              (Also same as reflux), Btu/lb or Btu/mol.
           Refer to Figure 8-53  (System (1)).
                                                                 5. For partial condenser: replace DhD by DHD in Step 3.
                                                                   A dew point on compositions of yD  (vapor) give tD  or
                                                                    total pressure. Also get liquid composition XD  (liquid
                                                                    reflux in equilibrium with product vapor YD.  Over-
                                                                    head vapor is sum of compositions of n, and xp. A
                                                                    dew  point  on  this vapor  (overhead from  tray  one
                   I-------------          1                        top)) gives top tray temperature, tl.



                                                                Reboiler Duty

                                                                 Refer to Figure 8-53 (System (2))

                                                                  1. Determine bottoms temperature by bubble point on
                                                                    liquid XB.
                                                                  2. From feed condition determine enthalpy.





                                                                  3. Solve for Qg, reboiler duty, Btu/hr
                    L ___----------                                 F hF + QJ  = DhD + BhB + Qc             (8 - 188)
                                           J
                                                                    where hn = total enthalpy of distillate product, Btu/mol
                                                                          -
                                                                                       *.
                      Figure 8-53. Heat balance diagram.                     or Btu/lb
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