Page 129 - Basic Gas Chromatography
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115                                   From   New York,                                          af     Miller,   1987,

                                          Perkin-Elmer.   Inc.,                                     i   700   From   York,  New




                                          of   Sons,   &                                            a   i   600   Perkin-Elmer.   Inc.,  Sons,

                          Air.  370  mL/min   Courtesy   :   .   Wiley  John   Inc.   Sons,         =   4   i   $00   (mi/min)   of  Courtesy   &   Wiley   Inc.
                                       Hydrogen  flow  rate  (mL/min)   response   FID   Contrasts,   &   Wiley   1   +   400   rate  Air  flow   response.   John  Contrasts,   Sons,   &






     (FID)                                on   rate   flow   and  Concepts   John   of              i   .   300   FID   on   rate   and   Wiley   John

     Detector                             hydrogen   Chromatography:   courtesy                     i   .   i   200   100   fiow   air   Concepts   of  courtesy



     Ionization   i           a.  5  mL/min  No   6.14  mU/min  No   ¢.  40  mL/min  No   d.75  ml/min  No   of  Effect   M.,   Reproduced   128.   1       of   Effect   Chromatography:   Reproduced


                       |
                             L
                             3
                       &
     Flame      3  (unuuprew  jo  %  S#)  asuodsau  20;99}8g       7.9.   Fig.   i   J.  Miller,   p.   1987,   saiodwe  g-O1X  esuodsey   7.10.   Fig.   M.,   J.   129.   p.






    Detectors   ECN                                                   Preston   mL/   not   significant   tailed   for   the   in   water,   Its   but
            Theoretical   2   2   6   0.5   15   2.5   2.5   3.5   45   MOF  AHKAMNOEAMINAMHOCORM   of   400   to   are   and   badly   used   be   interfere   in   the   FID.   ruggedness,   phases



          [15]*                                                       permission   300   of   7.10.   burn   Most   7.3.   produces   to   FID   not   of   simplicity,   glycol   liquid

         heptane)                                                     Science   by   value   Figure   not   Table   the   does  organic  contaminants   products.


         to                                                                    and   a   in   do   in   often   permits   it   characteristics   linearity,   polyethylene
         (relative   ECN   1.95   2.00   5.82   0.52   1.48   2.52   2.24   3.42   4,37   3.12   6.14   6.99   8.73   1.01   2.07   2.95   5.11   5.55   6.55   1.04   2.33   3.52   4.46   2.00   3.07   4.97   5.66   7.15   7.16   4.94   Chromatographic   Inc.   critical,   shown   carbon   listed   that   since   include   food   the   and

         Numbers                                                        Industries,   less   as   organic   ones   are   compound   water   for   water   and   summarizes   large   a   columns.   polyester   polymers.



         Carbon                                                      of  Journal   Preston   much   detectors,   containing   important   a  water,   peak   a   contain   applications   beverages,   sensitivity,   sizes   of   the   of   silicone

         Effective                                                   the   of   of   is   air   most   for   not   is   of   that   Typical   alcoholic   116   page   good   all   to   some   on


         FID                                             ketone   ketone   ketone   ketone   from   Division   rate   most   listed   absence   samples   other   on   are   hydrolyze   effect

         7.2   Compound      alcohol   aldehyde   acid   acid   acid   acid   acid   acid   acetate   acetate   acetate   acetate   ethyl   i-butyl   butyl   ketone   amyl   Reproduced   A   flow   sufficient   Compounds   The   those   The   of   chromatogram‘.   and   list   adaptability   may   no   to

   114   TABLE   Acetylene   Ethylene   Hexene   Methanol   Ethanol   n-Propanol   i-Propanol   n-Butanol   Amyl   Butanal   Heptanal   Octanal   Capric   Acetic   Propionic   Butyric   Hexanoic   Heptanoic   Octanoic   Methyl   Ethyl   i-Propyl   n-Butyl   Acetone   Methyl   Methyl   Ethyl   Di-i-butyl   Ethyl   Cyclohexanone   *   Publications,   The   min   is   detected.   among   peaks.   analysis   wine   The   advantages   and   “Water   it
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