Page 34 - Basic Gas Chromatography
P. 34
Overview 21 Devices Sampling and Inlets Sample INLETS SAMPLE of area Column Capillary Column Packed Split vaporizer Flash Splitless On-column and the On-column is p;, com Pressed in but column, the onto instantaneously injected is sample the Ideally, volumetric a as it introduce to is goal realistic more a and impossible is this practice narrow and
Instrument cross-sectional pressure inlet pressure, is gas e the to outlet. the outlet where flow outlet time, the volume is retention including quantitatively vely require
the under the the column; column the at the j: VII. retention samples and , types list:
by is pressure, Co nsequently, the the F,, factor, A ppendix a rete ntion adjusted DEVIC ES o f c olumn fo lowing
multipl ying IV. colu mn GC thro ugh head of meas ured is ra te, flow =] X F, the fro m resulting =j te F. with the variety r. apidly be Different the
by Gas a atmospheric pressure, po. passes it the rate flow average compressibility F. in given volume the V2: 7 Ve = confused SAMPLING wide a them to in
achieved Appendix Carrier entering at as from the so-called are retention and volume, VR be chapter. handle permit stream. indicated
is See of the gas usually outlet expands increases volumetric get of j a used, be not next the AND should and : gas as inlets
mL/min) (mr?). carrier is outlet than the and also the To the by values calculates should retention should in INLETS inlet solids, the carrier sample
(in column Compressibility the greater : inlet the rate Usually maximum. multiplied typical one rate term presented sample and of
20 rate the Since column at flow a and: Some If flow corrected This be SAMPLE The liquids, : into duced types