Page 34 - Basic Gas Chromatography
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Overview   21  Devices  Sampling   and  Inlets  Sample      INLETS  SAMPLE   of   area   Column  Capillary  Column  Packed      Split  vaporizer   Flash   Splitless  On-column   and   the  On-column   is   p;,   com  Pressed   in   but  column,   the   onto  instantaneously  injected   is  sample   the  Ideally,   volumetric   a   as   it  introduce   to   is   goal  realistic   more   a   and  impossible   is   this  practice   narrow   and




      Instrument   cross-sectional   pressure   inlet  pressure,   is   gas   e   the   to  outlet.   the   outlet  where   flow  outlet   time,   the   volume   is   retention   including   quantitatively  vely   require




             the        under   the   the   column;   column   the   at   the   j:   VII.   retention     samples   and   ,   types   list:
             by         is   pressure,   Co  nsequently,   the   the   F,,   factor,   A ppendix   a   rete ntion   adjusted   DEVIC ES   o f   c  olumn   fo lowing
             multipl ying   IV.   colu mn   GC   thro  ugh   head   of   meas ured   is   ra te,  flow   =]   X F,   the   fro m   resulting   =j te F.   with   the   variety   r.  apidly   be   Different   the




             by     Gas   a   atmospheric   pressure,   po.   passes   it   the   rate   flow   average   compressibility   F.   in  given   volume   the   V2:   7 Ve   =   confused   SAMPLING   wide   a   them   to   in
            achieved   Appendix   Carrier   entering   at   as   from   the   so-called   are   retention   and   volume,   VR   be   chapter.   handle   permit   stream.   indicated



            is   See   of   the   gas   usually   outlet   expands   increases   volumetric   get   of  j   a   used,   be   not   next   the   AND   should   and   :   gas   as  inlets
            mL/min)   (mr?).   carrier   is  outlet   than   the   and   also   the   To   the   by   values   calculates   should   retention   should   in   INLETS   inlet   solids,   the  carrier   sample



            (in   column   Compressibility   the   greater  :  inlet   the   rate   Usually   maximum.   multiplied   typical   one   rate   term   presented   sample   and   of
     20     rate   the   Since   column   at   flow   a    and:        Some   If   flow   corrected   This   be   SAMPLE   The   liquids,  :  into   duced   types
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