Page 65 - Biofuels Refining and Performance
P. 65

48   Chapter Two


                     Sunlight


                                           Enzymes
                   Chlorophyll
                                            RuDP
                                 ADP
           Water      ATP
                     NADPH                 Glucose   CO 2
              O 2
                                 NADP
                   Light reaction         Dark reaction
           Figure 2.2 General process of photosynthesis.




           independent (or dark reactions). The rate of the light reaction can be
           increased by increasing light intensity, and the rate of the dark reaction
           can be increased by increasing temperature to a certain extent (see Fig. 2.2).


           2.3.1  Hill reaction (light reaction)
           The process of formation of CO and O during photosynthesis is called
                                              2
                                       2
           the Hill reaction or photolysis of water. This primary photochemical
           reaction takes place in the presence of sunlight. The reaction is associ-
           ated with chlorophyll, and after receiving light energy, the chlorophyll
           becomes activated. The steps in the Hill reaction can be summed up in
           the following manner:

           1. Absorption of light and activation of chlorophyll     Radiant
              light contains very tiny energized particles called photons or quanta,
              which are absorbed by the chlorophyll and it becomes activated.
           2. Photolysis Is the dissociation of water molecules by light energy
              that have been absorbed by the chlorophyll. The reaction can be rep-
              resented as

                                    Light energy
                             4H O  ⎯⎯⎯⎯→ 4H   4OH
                                2
                                        Chlorophyll
                                  4H   ⎯⎯⎯⎯→ 2H      2
                       H   NADP → NADPH (Hydrogen acceptor)
                                            2
                        2
                                    Recombination
                             4OH   ⎯⎯⎯⎯⎯→ 2H O   O        2
                                                   2
   60   61   62   63   64   65   66   67   68   69   70