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Extraction, Refining, and Stabilization of Edible Oils    385


                                    Time of oxidation (hr)
                  0      1      2      3      4      5      6      7
               120

              Peroxide volue (milliequivalent peroxide/kg sample)
               100



                80



                60



                40



                20



                 0
                 25     50     75     100    125    150    175    200
                                      Temperature (°C)
          FIGURE 13.4  Peroxide values of fl axseed oil at different temperatures in the
          presence of air: without antioxidant (○); with antioxidant ( ). Peroxide values of
          fl axseed oil at different times in the presence of air at 30°C: without antioxidant
          ( ); with antioxidant ( ).


               antioxidants, such as, tocopherols, ascorbic acid, and β-carotenes. 28
               Black tea and green tea also have very good antioxidant potential. 29
               Extracts from grapes were also shown to exert good antioxidant
               activities, which proved beneficial in reducing the incidence of car-
               diovascular disease. 28



          13.6  Measuring Antioxidant Activities
               The efficacy of synthetic and natural antioxidants is measured by
               monitoring the oxidative stability of oil. After the sample is oxidized
               under standard conditions, the extent of oxidation is measured by
               chemical, instrumental, or sensory methods.
                   A variety of methods used to assess antioxidant activities includ-
               ing the following.
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