Page 230 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

Catalysts for Fine Chemical Synthesis: Hydrolysis, Oxidation and Reduction. Volume 1
Edited by Stan M Roberts and Geraldine Poignant
Copyright  2002 John Wiley & Sons, Ltd.
ISBN: 0-471-98123-0

Index

Absidia sp. 17 epoxidation 71±86
a-acetamido cinnamic acid non-asymmetric epoxidation 72±3
asymmetric hydrogenation 201±2 oxidation 20, 84
asymmetric reduction 184±6 almond meal 26
reduction by rhodium (B[3.2.0]DPO) amides, hydrolysis 4±9
complexes 185 a-amidoacrylate, hydrogenation 179±86
acetophenone amino acid anions 171
asymmetric hydrogenation 133±4 amino alcohol±borane complex 143
oxazaborolidine borane amino alcohols 160
reduction 146±8 amino borohydride anion unit
ÿ
17a-acetoxy-11-deoxycortisol 3 (NBH ) 145
3
N-acetylglucosamine 38 amonoindanol axazaborolidine,
acid phosphatase 28 sythesis 157
Acinetobacter calcoaceticus 24 p-anisaldehyde reagent, preparation 50
Acinetobacter sp. 24 aromatic ketones, asymmetric
acrylic acid derivatives 176 hydrogenation 127±34
acryloyl amide 30 aryl aldehydes 26
acyclic diene 31 Aspergillus sp. 17
acyclic dienol ester 33 asymmetric aminohydroxylation of
a-(acylamino)acrylic acids and esters, 4-methoxystryrene 103±5
Rh-catalyzed asymmetric asymmetric dihydroxylation of
hydrogenation 202 (1-cyclohexenyl) acetontrile 105±8
N-acyloxazolidinones, preparation of asymmetric epoxidation 51±3
optically active 188 allylic alcohols 73±81
acyloxyboron complexes 32 disubstituted E-alkenes 94±8
aldehydes 32 disubstituted Z-alkenes 88±93
alkaloid derivatives 22 (E)-benzylideneacetophenone 59±60
(Z)-alkenes 21 (E)-benzylidenecetophenone 66±9
alkenes (E)-UNDEC-2-EN-1-OL 81±4, 82±4
aminohydroxylation 19 using chiral modified diethylzinc 61±2
catalytic asymmetric epoxidation 51 using poly-D-leucine 56±61
dihydroxylation 19 asymmetric hydrogenation
epoxidation 87±102 a-acetamidocinnamic acid 201±2
hydrocyanation 35 acetophenone 133±4
reduction 13±16 g-(acylamino)-g,d-unsaturated-b-keto
alkylaryl ketones, reduction 11 esters catalysed by Rh[(COD)
(E)-2-alkyliden-1-oxo-1,2,3, ‡ ÿ
(S)-BINAP] CIO and RuBr 2
4
4-tetrahydronaphthalenes, [(S)-BINAP] 217
epoxidation 65 aromatic ketones 127±34
alkylidene malonates 30 carbon±carbon double bonds 175±212
allylic alcohols 14, 19, 20 dehydroamino acids 194±202
asymmetric epoxidation 73±81 a-enamides 176