Page 235 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

224 index

oxidative transformations 17±26 by nonmetallic catalysts 156
oxiranes, hydrolysis 4±9 carbonyl, by borane 144
5-oxohexanoic acid 10 carbonyl compounds 10±13
oxone 22 chloroacetophenone, using sulfoxamine
borane 153±5
Pd(PPh 3 ) 4 37 dialkylketones 11
pentane-2,4-dione 13 ketones
(R,R)-2,4-pentanediol 13 by borane catalysts 145
3-phenylcyclobutanone 24 using amino acid anions as catalyst
phosphino-oxazoline copper(II) and hydrosilane as oxidant
complex 33 169±72
Pichia farinosa 14 metal-catalysed mechanism 118
pig liver esterase (ple) 5 oxazaphosphinamide 148±50
pivaldehyde 25 reactions 9±16
polyamino acids 24 see also asymmetric reduction;
polyclonal antibody 34 enantioselective reduction;
poly-D-leucine hydrogen transfer reduction;
asymmetric epoxidation using 56±61 stereoselective reduction
synthesis 58±9 [Rh((R)-BiNAP)] complexes 186±9
poly-D-leucine catalyst 56 Rh(B[3.2.0]DPO) complexes 180±6
poly-L-leucine 24, 61 a-acetamido cinnamic acid reduction
poly(octamethylene tartrate) 84 by 185
poly(octamethylene-L-(‡)-tartrate, Rh-catalyzed asymmetric hydrogenation
synthesis 81±2 of a-(acylamino)acrylic acids and
poly(tartrate) 84 esters 202
porcine pancreatic lipase 6 Rh±DuPHOS 16
potassium caroate 22 Rh(I)±BINAPHOS 35
potassium ferricyanide 18 Rh(I) catalysts, asymmetric
potassium peroxomonosulfate 51 hydrogenation using 213±17
progesterone, hydroxylation 17 Rh(I) complexes 35
proline 172 Rhizopus sp. 17
(R)-N-propionyl-4,5,5-trimethyl- [Rh((S,S)-Me-BPE)] 177±8
1,3-oxazolidine-2-one, synthesis 189 [Rh((R,R)-Me-DuPHOS)] 179±80
N-(2-pryidinesulfonyl)-1-amino-2- Rhodococcus erthyrolpolis 8
indanol 169 Rhodococcus sp. SP361 9
Pseudomonas cepacia lipase 6 Ru(II)-(2-azanorbornyl-methanol)
Pseudomonas fluorescens lipase 6, 7 complexes 129, 134
Pseudomonas putida 5 Ru±BINAP 13, 14, 15, 117±21
N-(2-pyridinesulfonyl)-1-amino-2- Ru(II)-catalysed asymmetric
indanol, synthesis 166±7 hydrogenation 15
Ru(II) catalysts 192±3
racemic 4-bromophenyl methyl sulfoxide, asymmetric hydrogenation using
kinetic resolution 111±13 213±17
RAMA 28 Ru(II) porphyric 101
recrystallization of 2-bromo-(3-nitro-4- Ru(S)±tetrahydroBINAP 15
benzyloxyphenyl)ethanol 158±61
reduction Saccharomyses sp. 12
a-acetamido cinnamic acid, by salen±manganese complexes 88±93
rhodium (B[3.2.0]DPO) Schlenk tube 119±20
complexes 185 sialyl Lewis tetrasaccharide 38
acetophenone, by oxazaborolidine sodium hypochlorite 21
borane 146±8 stereoselective reduction
alkenes 13±16 2,3-butadione monoxime trityl
alkylaryl ketones 11 ether 161±2