Page 231 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

220 index

asymmetric hydrogenation (contd.) (S)-2-benzyloxymethylpropanal 14
ethyl 4-acetamido-3-oxo-5-phenyl-4- Betnovate 17
pentenoate 214±17 biaryl compound 31
keto esters 128 BINAL±H 11
‡
b-keto esters 121±3 [(BINAP)Rh(MeOH) 2 ] [ClO 4 ] ÿ 15
ketones 115±36 (R)-BINAP±RuCl 2 13
methyl-(Z)-3-phenyl-2-methyl- [(R-BINAP)RuCl
carboxamido-2- (m-Cl) 3 ][NH 2 (C 2 H 5 ) 2 ] 13
propenoate 209±10 BINAP±RuCl 2 11
using a metal catalyst 117±21 BINOL±TiCl 2 29
i
using Rh(I)- and Ru(II)- BINOL±Ti( PrO) 2 29
0
catalysts 213±17 (S,S)-1,1 -bis
vinylphosphonic acids 191±2 (a-acetoxyphenylmethyl)ferrocene,
asymmetric hydroxylation 103±8 synthesis 205±6
asymmetric oxidation (R,R, p S, p S)-1,1 -bis(a-acetoxypropyl)-
0
4-bromothioanisole 109±11 2,2 -bis(diphenyl-
0
methylsulfides 110 phosphino)ferrocene,
sulfides 109±13 preparation 198±9
asymmetric reduction (aS,a S)-1,1 -bis(a-N,N-
0
0
a-acetamido cinnamic acid 184±6 dimethylaminophenylmethyl)-
bromoketone 157±66 (R,R)-1,1 -
0
2-bromo-(3-nitro-4- bis(diphenylphosphino)ferrocene,
benzyloxy)acetophenone 157±8 synthesis 207±8
(Z)-N-carbobenzyloxy-3-ketoproline (S,S)-1,1 -bis(a-N,N-
0
ethylester, using bakers' dimethylaminophenylmethyl)
yeast 140±2 ferrocene, synthesis 206±7
0
carbonyl compounds, using bakers' (R,R, p S, p S)-1,1 -bis[a-
yeast 139 (dimethylamino)propyl]-2,2 -
0
chloroacetophenone 151±6 bis(diphenyl-phosphino)ferrocene,
ethyl acetoacetane 137±9 preparation 197±8
0
ketones 148 (R,R)-1,1 -bis[a-
prochiral ketone dimethylamino)propyl]ferrocene,
(chloroacetophenone) 167±8 preparation 196±7
using bakers' yeast 137±42 ( p S, p S)-1,1 -bis(diphenylphosphino)-2,2 -
0
0
using nonmetallic catalysts 143±73 bis(1-ethylpropyl)ferrocene
vinylphosphonic acids 192±3 [(S, S)-3-PT-ferrophos],
asymmetric ruthenium-catalysed preparation 199±200
hydrogenations 194 (S,S)-1,1 -bis
0
asymmetric sulfoxidation 109±13 (a-hydroxyphenylmethyl)ferrocene,
(1S,3R,4R)-2- synthesis 204±5
azanorbornylmethanol 127±34 (R,R)-1,1 -bis(a-hydroxypropyl)ferrocene,
0
2-azido-3-hydroxypropanal 28 preparation 195±6
bisisoxazolines 30
Baeyer±Villiger monooxygenases 24 BisP, synthesis and use as ligand 123±7
Baeyer±Villiger oxidation 24, 25 BisP±Ru, synthesis 125±6
Baeyer±Villiger reaction 24 bisphosphinite 35
bakers' yeast 14 preparation 182±3
asymmetric reduction using 137±42 bis(phospholane) ligands 121
immobilization 140 3,5-bis-trifluorophenyl 35
Beauvaria sulfurescens 8, 9 borane, carbonyl reduction by 144
benzomorphans 14 borane complexation with valinol 144
N-benzylcinchoninium salt 34 borane±dimethylsufide (BH 3 .SMe 2 ) 143
(E)-benzylideneacetophenone, asymmetric borane±tetrahydrofuran (BH 3 .THF) 143
epoxidation 59±60 Brevibacterium sp. R312 9