Page 234 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

index 223

(1S,3R,4R)-3-hydroxymethyl-2- (S)-2-methyl-2,3-butanediol,
azabicyclo[2.2.1]heptane, synthesis 187±8
sythesis 131±2 (R)-(ÿ)-methyl-3-hydroxypentanoate,
6-hydroxynicotinic acid 17 synthesis 126±7
(R)-2-(4-hydroxyphenoxy)propanoic methyl-3-oxobutanoate 13
acid 17 methyl-3-oxo-2-trityloxyiminostearate,
b-hydroxysulfoxamine borane, stereoselective reduction 163±4
preparation 151±3 (E)-2-methyl-3-phenyl-2-propenol,
hydroxysulfoximines 12 epoxidation 76±8
(Z)-methyl styrene, epoxidation 89±90
2-isobutylidene-1-tetralone, methyl para-tolyl sulfide 25
epoxidation 62±3 oxidation 26
4-methylene-N-acyloxazolidinone,
Katsuki±Sharpless oxidation 20, 21 hydrogenation 186±9
keto esters, asymmetric methylene chloride 15
hydrogenation 128 (1R,2R)-N-methylpseudoephedrine 65
b-keto esters, asymmetric (E)-b-methylstyrene 22
hydrogenation 121±3 enantioselective epoxidation 99±101
ketones 22, 23 methylsulfides,asymmetricoxidation 110
asymmetric hydrogenation 115±36 morphinans 14
asymmetric reduction 148 Mosher esters, preparation 171
enantioselective reduction using MTPA chloride, derivatization with 75±6
N-arylsulfonyl Mucor sp. 17
oxazaborolidines 166±8 Mukaiyama coupling 28
hydrogen transfer reduction 134
reduction by borane catalysts 145 NaHCO 3 22
reduction using amino acid anions as NaOH 34
catalyst and hydrosilane as naphthyl constituent 192±3
oxidant 169±72 naproxen precursor 36
kinetic resolution of racemic [NH 2 (C 2 H 5 ) 2 ] 13
4-bromophenyl methyl nickel±DIOP system 35
sulfoxide 111±13 Ni(COD) 2 35
kinetic resolution of sulfoxides 109±13 nitriles, hydrolysis 4±9
non-asymmetric epoxidation 55±6
La-(R)-BINOL-Ph 3 PO/cumene allylic alcohols 72±3
hydroperoxide system 66±9 nonmetallic catalysts
Lactobacillus sp. 11 asymmetric reduction using 143±73
lanthanoid±BINOL complexes 23 reduction by 156
leucine N-carboxyanhydride, nonracemic chiral epoxides 51
synthesis 57±8
n-octane 7
maleimide 31 olefin hydrogenation by transition metal
manganese(III) complex 88 complexes 177
manganese±salen complex 21 organometallic catalysts 175±212
Manihot esculenta 27 oxabicyclooctene 34
(S)-Me-CBS 148 oxazaborolidine borane reduction of
MeCN 3 Mo(CO) 3 37 acetophenone 146±8
(Me 3 CO 2 C) 2 CMe 2 31 oxazaborolidines 32
menthol 30 oxazaphosphinamide borane reduction of
metal-catalysed reduction chloroacetophenone 148±50
mechanism 118 oxazaphosphinamides 12
methacrolein 31 oxidation
4-methoxystryrene, asymmetric (Z)-allylic alcohols 84
aminohydroxylation 103±5 homoallylic alcohols 84