Page 236 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

index 225

methyl 3-oxo-2- trans-2-acetylaminocyclohexanol 7
trityloxyiminostearate 163±4 transition metal complexes, olefin
1-(tert-butyldimethylsilyoxy)-3-oxo-2- hydrogenation by 177
trityloxyiminooctadecane 164±6 (S)-4,4,5-trimethyl-1,3-dioxolane-2-one,
sulfides, asymmetric oxidation 109±13 synthesis 186±7
sulfonamine catalyst 151±6 1-trimethylsilyloct-(1E)-en-3-ol 21
sulfoxamine borane, chloroacetophenone triphosgene 58
reduction using 153±5 trisubstituted alkene 87
sulfoxides, kinetic resolution 109±13
sylyl enol ethers 30 (E)-UNDEC-2-EN-1-OL, asymmetric
sylylketene acetals 30 epoxidation 81±4
a,b-unsaturated carbonyl compounds,
TBHP 20, 68 epoxidation of 55±69
tert-butyldimethyl silyl 29 a,b-unsaturated ketones, epoxidation
1-(tert-butyldimethylsilyoxy)-3-oxo-2- 55±6
trityloxyiminooctadecane, urea±hydrogen peroxide 24
stereoselective reduction 164±6
tert-butyl hydroperoxide 23 valinol, borane complexation with 144
tert-butyl methyl ether 6 vinyl acetate 6, 7
THF 23, 24 vinylphosphonic acids
thin layer chromatography (TLC) 50, 61 asymmetric hydrogenation 191±2
L-threonine aldolase 28 asymmetric reduction 192±3
Ti(O±i-Pr) 4 21 enantioselective ruthenium-catalyzed
i
Ti(O Pr) 4 25 hydrogenation 190±4
Ti(O±i-Pr) 4 (‡)-diethyl tartrate 20
titanium chiral complex 73±81 Xanthomonus orysae 28
titanium±TADDOL system 33
titanium tetra-isopropoxide 19 Yamadazyma farinosa 10, 14
titanium(IV) chiral complex 71, 72
TMS 27 Zimmerman±Traxler transition state
toluene 34 30