Page 303 - Challenges in Corrosion Costs Causes Consequences and Control(2015)
P. 303

SHIPS                                                           281

            TABLE 4.39 Performance of Plain Steel, Prepainted Steel, and Zn/Zn Coated Steels
                                              Number of Perforations
            Auto Part         Plain Steel    Prepainted Steel   Zn/Zn Alloy Coated
            Hoods               1.75              0.5                  0
            Fenders             0.30              0.8                  0
            Doors                –                0.7                  0
            Quarter panels       2.4              0.3                 0.5
            Deck/hatch           1.0              0.1                 0.0


            TABLE 4.40 Two Methods of Phosphating on Automobiles
                                               Average Defect Size (inches)
            Year                     Spray                         Immersion
            1980                     19.8                             –
            1981                      6.2                             –
            1988                      9.0                            3.5
            1989                      3.5                            0.2


            two methods of phosphating. The resulting data from the two methods are shown in
            Table 4.40.
              It is very obvious from the above data that the total immersion method of phos-
            phating is far superior to the spray method of phosphating.
              The use of electrocoat or e-coat paints and primers is another technology that found
            extensive use in the 1980s. Electrocoated paint is applied on the part to be coated in a
            paint bath, and electrical current is applied. This method enables painting of the most
            intricate parts. The electrocoated automobiles were more corrosion resistant. The sur-
            face rust was approximately three times higher, and the number of perforations were
            also higher in vehicles that were treated in the standard conventional manner. Some
            of these differences may be because of zinc coating on the steel and phosphatizing.
            However, electroplated paint systems had a noticeable effect on corrosion resistance.


            4.22  SHIPS

            Corrosion control of ships can be accomplished in (i) the design phase; (ii) manufac-
            turing phase; and (iii) operation phase.

            4.22.1  Design
            There are several elements that can reduce the amount of corrosion in the ship’s life-
            time. The design of a ship to have minimal discontinuities, such as sharp corners, will
            reduce the surfaces where coatings are most likely to fail.
              Design can also be made to minimize locations with stress concentration, which
            can act as crack initiation sites and locations where coatings can crack. The design
   298   299   300   301   302   303   304   305   306   307   308