Page 323 - Challenges in Corrosion Costs Causes Consequences and Control(2015)
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PULP AND PAPER INDUSTRIAL SECTOR                                301

            resulting corrosion can be controlled. Another useful practice consists of scheduled
            cleaning and proper equipment maintenance to prevent the buildup of pulp and
            decrease the amount of stagnant solutions.

            4.29.2  Process Design and Corrosion Inhibitors

            Corrosion rates in mill equipment also depend on the chemical composition within
            each section of the process. The chemical composition varies from mill to mill
            depending on the processes involved, the closure of the mill’s systems, the desired
            paper grade, the speed of the process, and the amount of pulp or paper being
            produced.
              In general, the corrosivity of an environment will increase with an increase in
            temperature, low pH, dissolved solids content, and chloride and sulfur compound
            concentrations. Thus by monitoring the process and maintaining the proper temper-
            ature, pH, dissolved solids content, chloride, and sulfur compound concentration the
            extent of corrosion can be controlled.
              In some processes, addition of corrosion inhibitors can control the corrosion. Mea-
            surements of the process chemistry should be made to ensure that the correct dosage
            of inhibitor is maintained.
              Corrosion control in the pulp and paper industry consists of verification of average
            corrosion rates, using weight loss coupons, regular inspection, and preventive main-
            tenance. Preventive strategies are considered during design and construction phases
            when new equipment is considered or existing equipment is refurbished or repaired.
            Corrosion prevention techniques minimize corrosion initiation altogether, while cor-
            rosion control techniques minimize the propagation of ongoing corrosion.


            4.29.3  Weight Loss Coupons
            Weight loss in coupons exposed to the corrosive medium gives the average corrosion
            rate in the atmosphere of a pulp or paper plant. This technique is cheap and easy
            to use as it involves the determination of weight of metal coupons before and after
            exposure for a known length of time. From the loss in weight of the coupon, the
            average corrosion rate can be calculated. An advantage of this technique is that several
            coupons of different materials can be exposed to the environment simultaneously.
              By performing weight loss tests, technical personnel can estimate the corrosive-
            ness of an environment over a period of time. If the corrosion rate is determined to
            be high, preventive measures can be taken to prolong the remaining life of the equip-
            ment. The preventive measures can include the addition of a corrosion inhibitor, a
            change in the process, an application of anticorrosion coatings, or the addition of a
            CP system.


            4.29.4  Inspection and Preventive Maintenance
            An additional and simplest and obvious method to monitor the corrosion rate is
            through visual inspection of all parts of the equipment that are exposed to corrosive
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