Page 109 - Chemical and process design handbook
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Speight_Part II_A  11/7/01  3:16 PM  Page 2.50







                  2.50                  MANUFACTURE OF CHEMICALS

                                             Hydrogen and nitrogen recycle





                       Hydrogen




                                                        Reactor                Separator
                      Compressor





                       Nitrogen




                                                                        Liquid ammonia
                  FIGURE 1  Ammonia manufacture from hydrogen and nitrogen by the Haber process.


                                 Shift converter    Methanator         Separator
                                          Carbon dioxide       Ammonia
                       Reformer
                                            removal            converter
                                                                             Flash gas













                  Desulfurized naphtha
                     or natural gas       Carbon dioxide              Ammonia
                  FIGURE 2  Ammonia manufacture from natural gas or naphtha.


                  oxygen of the air reacts with the hydrocarbon feedstock in combustion and
                  helps to elevate the temperature of the reformer. Otherwise nitrogen can be
                  added from liquefaction of air. In either case a hydrogen-nitrogen mixture
                  is furnished for ammonia manufacture.
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