Page 314 - Chemical process engineering design and economics
P. 314

Separator Design                                              293


            move downward or upward toward the interface, depending on the specific gravity
            of the two liquids. Then,  at the interface,  drops will accumulate before  coalescing
            with one of the phases.
                 To prevent  entraining  either  the  light  or heavy phase  in the  outlet  streams,
            the  liquid  velocity in both outlet nozzles should be  low. According to Jacobs and
            Penny  [17], the liquid velocity in each outlet nozzle  should not be  any more than
            10 times the average velocity  of each phase in the decanter.  This rule  allows  siz-
            ing the outlet nozzles.
                 If  either  a  surface-active  agent  or  a  dispersion  of  fine  solids  is  present,  a
            stable  emulsion  could  form,  which  is  analagous  to  foam  in  a  gas-liquid  system.
            The  emulsion or  "rag" accumulates and  will eventually have to be removed  from
            the  decanter  using  valves  located  at  the  end  of  the  vessel.  After  removal,  the
            emulsion  can  be  de-emulsified  by  filtration,  heating,  adding  chemical  de-
            emulsifying  agents, or reversing the phase that is dispersed.
                 There appears to be no  satisfactory  sizing procedure  for decanters.  Drown
            and  Thomson  [18]  compared three  sizing procedures  and  found  that  all were un-
            satisfactory.  We will develop a simple method here to illustrate  some of the  fac-
            tors  involved  and  to obtain  a preliminary estimate  of the  decanter  size. Accurate
            sizing  must  be  supplemented  by  testing.  Even  though  settling  and  coalescing  of
            drops occur  simultaneously,  it will be  assumed that  first  the  drops flow  to the in-
            terface,  and then the drops coalesce with the appropriate phase. This simple model
            is illustrated in Figure 6.7.
                 The  first  step in developing a sizing procedure  is to determine which phase
            is  dispersed.  Selker  and  Sleicher  [19]  found  that  the  value  of  the  parameter  6,
            defined  by Equation 6.15.1 in Table  6.15,  could be used  as a guide to  determine
            the  dispersed  phase.  After  calculating  0,  then use  Table  6.13  to  identify  the  dis-
            persed phase.




                                                              J

                                 i o°° °  ° o° t  °  o                   r~  Hi>
                                 '  O  O  o  O O o        4
                                                           T
                                 ! o o  o  °  o  o  o  °o o0 0°  °o o  o „ o O O  o o o o  o
                                                  0
                                         o °  o  o » ° 0 o 0 0 0  » V °  0 0 0  °
                                  o° o° 0         0
                                   ".•.•.V.'S"            t
                                                               H.D


            Figure 6.7  An idealized liquid-liquid-separator model.






         Copyright © 2003 by Taylor & Francis Group LLC
   309   310   311   312   313   314   315   316   317   318   319