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Physical Chemistry         27


                 A. Water and methane

                             δ
                            +0.3                   H O                    CH 4              H
                                                    2
                             H
                                                  18 Da    Molecular mass  16 Da
                                                 +100 °C    Boiling point  -162 °C

                                                              Heat of                H
                                                   41       vaporization    8
                                                                   -1
                                                            (kJ · mol )                                H
                  δ                    H    δ      6.2    Dipole moment     0         H
                -0.6                      +0.3              (10 -30  C · m)



                       Water (H O)                                                     Methane (CH )
                               2
                                                                                                   4
                 B. Structure of water and ice



                                                     Liquid water
                                                     density 1.00 g · cm -3
                                                      short-lived clusters















                  2.                                                                3.
                                               Ethanol
                                                           Ice
                                                     Density 0.92 g · cm -3
                                                      hexagonal lattice,
                                                        stabilized by
                 1.                                   hydrogen bonds



                 C. Hydration




                                    Cation







                              O H
                      H O

                           H O
                  Glycerol


                                                 Anion
                                                                                     [Me (H O) ] 2
                                                                                             6
                                                                                          2

           Koolman, Color Atlas of Biochemistry, 2nd edition © 2005 Thieme
           All rights reserved. Usage subject to terms and conditions of license.
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