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20    C h a p t e r   2                                                                                                             C o r r o s i o n   B a s i c s    21



                  Sample
                  Description      Chemical or Mineral Name*  Chemical Formula*
                  Product formed   Nesquehonite             MgCO ·3H O
                                                                    2
                                                                3
                  on magnesium     Calcium fluosilicate     CaSiF
                                                                6
                  during 3-month   Beta silicon carbide     b  -SiC
                  immersion in tap   Sodium sulfide         Na2S
                  water            Sodium fluoride          NaF
                                   Magnesium carbonate      MgCl ·2MgCO
                                                                2
                                                                       3
                                   Chloride hydroxide hydrate   Mg(OH) ·6H O
                                                                     2
                                                                  2
                                   Magnesium pyrophosphate   Mg P O
                                                                  7
                                                              2 2
                                   Anorthoclase             (Na,K)AlSi O
                                                                    3
                                                                     8
                                   Alpha cristobalite       SiO
                                                               2
                                   Sodium hydroxide         NaOH
                                   Calcium aluminum oxide   Ca Al O SO 4
                                                                  12
                                                              4
                                                                6
                                   sulfate
                  Substance        Halite                   NaCl
                  found on heat
                  exchanger
                  Substance found   Alpha quartz            SiO 2
                  beneath paint on
                  metal surface
                  Product formed   Lepidocrocite            g   -Fe O ·H O
                                                                    2
                                                                 3
                                                               2
                  on automobile    Goethite                 Fe O ·2H O
                                                                   2
                                                               3
                                                              2
                  bumper support
                  during 3-year
                  service
                  Product from     Zinc ferrite             ZnO·Fe O
                                                                 2
                                                                   3
                  conversion       Cobalt ferrite           CoO·Fe O
                                                                   3
                                                                 2
                  unit in marine   Cobaltous ferrite        CoO·Fe O
                                                                 2
                                                                   3
                  environment      Halite                   NaCl
                                   Chromic oxide            Cr O
                                                             2
                                                               3
                                   Nickel, zinc ferrospinel   (Ni,Zn)O·Fe O
                                                                     2
                                                                      3
                                   Sodium fluothorate       Na Th F
                                                              3
                                                                2 11
                                   Embolite                 Ag(Cl,Br)
                                   Magnesioferrite          MgFe O
                                                                2
                                                                  4
                                   Beryllium palladium      BePd
                                   Magnetite                Fe O
                                                               4
                                                              3
                                   Nickel titanium          NiTi
                  Product formed on   Botallackite          CuCl ·3Cu(OH) ·3H O
                                                                       2
                                                               2
                                                                           2
                  copper during 3-  Ilvaite                 Ca(Fe,Mn,Mg) (Fe,Al)
                                                                       2
                  month immersion                             (SiO ) OH
                                                                4 2
                  in tap water
                 TABLE 2.1  Results of X-Ray Diffraction of Products Found on Specimens Exposed
                 to Real Environments [1]
   33   34   35   36   37   38   39   40   41   42   43