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118  Chapter 4 Process Synthesis and Design Optimization

                                                                      Q Q
                                                                       1+2 tot
                                                             Q
                        Q 1                                    2
                                                       T
                   F           ∆ T                          P   T       F



                                                                     STEAM






                   T


                 Fig. 4.29. Heat integration between processes with a control
                 configuration to absorb disturbances by heat balance control.

                 way to deal with these disturbances, and immediate compensation for the disturban-
                 ces and de-coupling of interactions are ways to do this. Figure 4.29 shows an exam-
                 ple of compensation for disturbances for heat exchange between two sections. The
                 subject of controllability analysis is discussed in detail in Chapter 8.

                 Safety and environmental  In Section 4.1.2, constraints were discussed from safety
                 and environmental points of view. Although HAZOP studies will draw attention to
                 these problems, they do so far too late in the design, and there will be a need for
                 add-on provisions. Particular attention must be given to streams that are directly
                 coupled with other processes, as any upset may lead to serious problems ± perhaps
                 unexpected impurities, a major change in pH, or an oil layer on water (or vice
                 versa). Special attention must be paid to heat-exchanging streams, as these have a
                 tendency to leak over time, potentially leading to problems of inter-reactivity
                 between streams. Special consideration must also be given to temperature-sensitive
                 materials, particularly under low-or no-flow conditions in heaters, as steam control
                 valves always leak and may cause problems of inter-reactivity or plugging. Unexpec-
                 ted situations may also occur with regard to environmental problems.
                   In conclusion, it might be said that concern exists regarding inter-process connec-
                 tions as a result of integration between processes. Potentially serious problems that
                 may occur during upsets are not limited to direct connections but also indirectly in
                 heat exchangers. In this respect, the design should be driven especially by inherently
                 safer conditions.

                 Economical  Economical constraints speak for themselves, although often there is a
                 tendency not to take the full cost and realistic savings in consideration. The cost of
                 provisions for back-up, controllability, and operability are often not (or are insuffici-
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