Page 76 - Dust Explosions in the Process Industries
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Dust Explosions: An Overview  49


               between initial pressure and maximum explosion pressure up to very high initial pres-
               sures, approaching 100 bar.
                 Figure 1.54 also gives the maximum rate of pressure rise as a function of initial pres-
               sure. The excellent linear correlation is the result of  somewhat arbitrary adjustment of
               the dust dispersion conditions with increasing quantities of dust to be dispersed.
                 The more arbitrarynature of the rate of pressurerise is reflectedby the data in Figure 1.55,
               which show that in Wiemann's experiments (dPldt),,  started to level out and depart from
               the linear relationship for initial pressures exceeding 2 bar (abs).


                   600
               - -    - -
                              POWDER
                       POLYMER
                VI
                VI
               \
               \       POLYMER POWDER
                E     -  (WALTHER  AND   SCHACKEI
                      - (WALTHER AND  SCHACKEI
                   400
                E  400
                m
               n
               m      - -
                X
                   200
                9  200  - -
               +
               U
                                            +o  I  mivessel
                                  OWN COAL
               \                  OWN COAL   +o  I  mivessel
               CL     - -
               E
                                                 20
                                              0  20 I-sphere
                                                   I-sphere
                                              0
                      .do
                    0  .do     I  I    I  I     I  I    I  I
                    0
                      0       1        2        3       4        5
                                 INITIAL  PRESSURE  Ibar  (abs.)]
               Figure 1.55  Normalized highest  (dP/dt),,,  as a function of initial pressure for explosions of poly-
               mer and brown coal dust in closed compatible  I  m3 and 20 liter  vessels (Data from Walther and
               Schacke, 7986, for polymer, and Wiemann,  1987, for brown coal).
                 Figure 1.56 illustrates how the minimum explosible concentration of dusts increases
               systematicallywith increasing initial pressure. Hertzberg and Cashdollar (1988) attrib-
               uted the close agreement between polyethylene  and methane to fast and complete
                    150
                                 COAL      .'"'  POLYETHYLENE




                                     I            I
                       0             1            2            3
                                INITIAL PRESSURE  Ibar (abs.11

               Figure 1.56  Influence of initialpressure on the minimum explosible concentration of two dusts and
               methane in air (From Hertzberg and Cashdollar, 1988).
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