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100     PART II • Tectonic-Scale Climate Change


            0                                                  The most important climatic record in the ocean is
                                                            the oxygen isotope signal (see Appendix 1 for a full
                                                            summary). Most of the oxygen in nature occurs as the
                                                            very abundant  O isotope or as the much less abundant
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           10
                                                            18 O isotope. Scientists refer to changes in the relative
                                                            amounts of these two isotopes as variations in  δ O,
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                                                            measured as changes in parts per thousand (‰).
           20                                                                 18
                                                               Typical modern δ O values are 0 to –2‰ for the
                                                            surface ocean, +3 to +4‰ for the deep ocean, and –30
          Myr ago  30                                       to –55‰ for ice sheets (Figure 6-6). Changes occur
                                                            through time in the δ O values of water in the ocean
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                                                            and of ice in the glaciers. In this chapter the main focus
                                                            is on changes in δ O values in the ocean. Foraminifera
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           40                                               living both in surface waters and on the seafloor use
                                                            HCO ions dissolved in seawater as the source of car-
                                                                  –
                                                                 3
                                                            bon and oxygen for their CaCO shells. Because the
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                                                                          –
           50                                               oxygen in HCO comes directly from seawater, it gives
                                                                          3
                                                            climate scientists information on past variations in the
                                                            two isotopes of oxygen in the ocean, as quantified by the
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           60                                               δ O signal.
              10       15        20        25        30        In the past, δ O variations have been produced by
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                 Estimated mean annual temperature (˚C)
                                                            two climatic factors: (1) changes in the temperature of
        FIGURE 6-5 Cooling in western North America         ocean water and (2) changes in the size of ice sheets on
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        Temperature trends estimated from the outline shapes of fossil  the continents. Changes in δ O values measured in the
        leaves indicate an erratic but progressive cooling of northern  foraminiferal shells decrease by 1‰ for each 4.2°C
        middle latitudes during the last 55 Myr. (Adapted from J. A.  increase in the temperature of ocean water at the loca-
        Wolfe, “Tertiary Climatic Changes in Western North America,”  tion where the foraminifera lived. The same relation-
        Palaeogeography, Palaeoclimatology, Palaeoecology 108 [1994]:  ship holds if seawater cools but in the reverse sense
        195–205.)                                           (δ O values become heavier).
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                                                               Changes in size of the ice sheets also alter δ O val-
                                                            ues in foraminiferal shells. Ice sheets are formed from
        have irregular edges, jagged or serrated in outline. The  water vapor evaporated from the oceans and later pre-
        reason for this relationship is not known, but the corre-  cipitated as snow (Appendix 1). Because the snow and
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        lation with temperature in the modern vegetation is  ice are enriched in the lighter  O isotope, more of the
        strong enough that climate scientists have used this  heavier  O isotope is left behind in the oceans. This
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        relationship to estimate past temperatures from assem-  enrichment process is called fractionation. As a result,
        blages of fossil leaves preserved in sedimentary rocks.  the δ O value of ocean water becomes more positive as
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           One record derived from leaf-margin evidence in  ice sheets grow.
        western North America shows an ongoing cooling over
        the last 50 Myr (Figure 6-5). Although interrupted by
        small warm intervals, the trend toward ever-lower tem-
        peratures persists over the long term.
                                                             Poles           Middle latitudes      Tropics
        6-2 Evidence from Oxygen Isotope Measurements          Ice
                                                            –30      –55
        Evidence of climate change on the continents over the         River  –15           Surface  0        –2
                                                                                            ocean
        last 50 Myr is incomplete. The first occurrences of ice
        sheets on land and their subsequent fluctuations in                             Deep ocean  +3        +4
        size are difficult to define. In addition, lakes that accu-
        mulate remains of past continental vegetation in their
        muddy sediments rarely persist for millions of years. In  FIGURE 6-6 Typical δ O values in the modern world
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        contrast, parts of the deep ocean have accumulated a  δ O values in the ocean vary from 0 to –2‰ in warm tropical
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        continuous climatic record with quantitative informa-  surface waters today to as much as +3 to +4‰ in cold deep-
        tion about climate change across the entire 50-Myr  ocean waters. In today’s ice sheets, typical δ O values reach
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        interval.                                           –30‰ in Greenland and –55‰ in Antarctica.
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