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260                           Magnetic materials

                                   11.2  Macroscopic approach
                                   By analogy with our treatment of dielectrics, I shall summarize here briefly the
                                   main concepts of magnetism used in electromagnetic theory. As you know, the
                                   presence of a magnetic material will enhance the magnetic flux density. Thus
                                   the relationship
                                                              B = μ 0 H,                    (11.1)

     M is the magnetic dipole moment  valid in a vacuum, is modified to
     per unit volume, or simply, mag-
     netization.                                           B = μ 0 (H+M)                    (11.2)

                                   in a magnetic material. The magnetization is related to the magnetic field by
                                   the relationship

     χ m is the magnetic susceptibility.                     M = χ H.                       (11.3)
                                                                   m
                                   Substituting eqn (11.3) into eqn (11.2) we get

     μ r is called the relative permeabil-            B = μ 0 (1 + χ m ) H = μ 0 μ r H.     (11.4)
     ity.
                                   11.3  Microscopic theory (phenomenological)

                                   Our aim here is to express the macroscopic quantity, M, in terms of the
                                   properties of the material at atomic level. Is there any mechanism at atomic
                                   level that could cause magnetism? Reverting for the moment to the classical
                                   picture, we can say yes. If we imagine the atoms as systems of electrons orbit-
                                   ing around protons, they can certainly give rise to magnetism. We know this
                                   from electromagnetic theory, which maintains that an electric current, I, going
     ∗  It is an unfortunate fact that the usual  round in a plane will produce a magnetic moment, ∗
     notation is μ both for the permeability
     and for the magnetic moment. I hope                      μ m = IS,                     (11.5)
     that, by using the subscripts 0 and r for
     permeability and m for magnetic mo-
     ment, the two things will not be con-  where S is the area of the current loop. If the current is caused by a single
     fused.                        electron rotating with an angular frequency ω 0 , then the current is eω 0 /2π,
                                   and the magnetic moment becomes

                                                                  eω 0 2
                                                            μ m =    r ,                    (11.6)
                                                                   2
                                   where r is the radius of the circle. Introducing now the angular momentum
                                                                   2
                                                               = mr ω 0 ,                   (11.7)
     Remember that the charge of the  we may rewrite eqn (11.6) in the form,
     electron is negative; the magnetic
                                                                   e
     moment is thus in a direction op-                       μ m =   .                      (11.8)
     posite to the angular momentum.                              2m
                                     We now ask what happens when an applied magnetic field is present. Con-
                                   sider a magnetic dipole that happens to be at an angle θ to the direction of the
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