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or
                                                    c
                                         c
                                                                             c
                                                                c
                                        ˜   (r, −ω) = ˜  (r,ω),  ˜   (r, −ω) =−˜  (r,ω).
                                         ij         ij          ij           ij
                        For an isotropic material it takes the particularly simple form
                                                      ˜ σ      ˜ σ
                                                  c
                                                 ˜   =  + ˜  =   +   0 +   0 ˜χ e ,            (4.26)
                                                     jω       jω
                        and we have
                                                                c
                                                                             c
                                                    c
                                         c
                                        ˜   (r, −ω) = ˜  (r,ω),  ˜   (r, −ω) =−˜  (r,ω).       (4.27)
                        4.4.2   High and low frequency behavior of constitutive parameters
                          At low frequencies the permittivity reduces to the electrostatic permittivity. Since ˜
                        is even in ω and ˜  is odd, we have for small ω



                                                     ˜   ∼   0   r ,  ˜   ∼ ω.
                        If the material has some dc conductivity σ 0 , then for low frequencies the complex per-
                        mittivity behaves as
                                                    c
                                                   ˜   ∼   0   r ,  ˜   c    ∼ σ 0 /ω.         (4.28)
                          If E or H changes very rapidly, there may be no polarization or magnetization effect at
                        all. This occurs at frequencies so high that the atomic structure of the material cannot
                        respond to the rapidly oscillating applied field. Above some frequency then, we can
                        assume ˜ ¯χ = 0 and ˜ ¯χ = 0 so that
                                e
                                           m
                                                                 ˜
                                                      ˜
                                                      P = 0,    M = 0,
                        and
                                                    ˜
                                                                       ˜
                                                                ˜
                                                          ˜
                                                    D =   0 E,  B = µ 0 H.
                        In our simple models of dielectric materials (§ 4.6) we find that as ω becomes large
                                                            2
                                                                          3

                                                 ˜   −   0 ∼ 1/ω ,  ˜   ∼ 1/ω .                (4.29)

                        Our assumption of a macroscopic model of matter provides a fairly strict upper frequency
                        limit to the range of validity of the constitutive parameters. We must assume that the
                        wavelength of the electromagnetic field is large compared to the size of the atomic struc-
                        ture. This limit suggests that permittivity and permeability might remain meaningful
                        even at optical frequencies, and for dielectrics this is indeed the case since the values of
                                                    ˜
                        ˜
                        P remain significant. However, M becomes insignificant at much lower frequencies, and
                                                      ˜
                                                            ˜
                        at optical frequencies we may use B = µ 0 H [107].
                        4.4.3   The Kronig–Kramers relations
                          The principle of causality is clearly implicit in (2.29)–(2.31). We shall demonstrate
                        that causality leads to explicit relationships between the real and imaginary parts of the
                        frequency-domain constitutive parameters. For simplicity we concentrate on the isotropic
                        case and merely note that the present analysis may be applied to all the dyadic com-
                        ponents of an anisotropic constitutive parameter. We also concentrate on the complex
                        permittivity and extend the results to permeability by induction.




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