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Figure 4.6: Arc plots for Debye and Cole–Cole descriptions ofa polar material.


                        Here   s is the real static permittivity obtained when ω → 0, while   ∞ is the real “optical”
                        permittivity describing the high frequency behavior of ˜ . If we split (4.106) into real and
                        imaginary parts we find that

                                                                         ωτ(  s −   ∞ )
                                                      s −   ∞

                                        ˜   (ω) −   ∞ =    ,    ˜   (ω) =−          .
                                                        2 2
                                                                                2 2
                                                    1 + ω τ                1 + ω τ
                        For a passive material we must have ˜  < 0, which requires   s >  ∞ . It is straightforward

                        to show that these expressions obey the Kronig–Kramers relationships. The details are
                        left as an exercise.
                          A plot of the Debye spectrum of water at T  = 20 C is shown in Figure 4.5, where we
                                                                     ◦

                        have used   s = 78.3  0 ,   ∞ = 5  0 , and τ = 9.6 × 10 −12  s [49]. We see that ˜  decreases
                        over the entire frequency range. The frequency dependence of the imaginary part of the
                        permittivity is similar to that found in the resonance model, forming a curve which peaks
                        at the critical frequency
                                                         ωmax = 1/τ
                        where it obtains a maximum value of

                                                                 s −   ∞
                                                      −˜  max  =      .

                                                                  2
                        At this point ˜  achieves the average value of   s and   ∞ :

                                                                  s +   ∞

                                                       (ωmax ) =       .
                                                                   2
                        Since the frequency label is logarithmic, we see that the peak is far broader than that
                        for the resonance model.

                          Interestingly, a plot of −˜  versus ˜  traces outa semicircle centered along the real axis

                        at (  s  +   ∞ )/2 and with radius (  s  −   ∞ )/2. Such a plot, shown in Figure 4.6, was first
                        described by K.S. Cole and R.H. Cole [38] and is thus called a Cole–Cole diagram or “arc



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