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Figure 4.6: Arc plots for Debye and Cole–Cole descriptions ofa polar material.
Here s is the real static permittivity obtained when ω → 0, while ∞ is the real “optical”
permittivity describing the high frequency behavior of ˜ . If we split (4.106) into real and
imaginary parts we find that
ωτ( s − ∞ )
s − ∞
˜ (ω) − ∞ = , ˜ (ω) =− .
2 2
2 2
1 + ω τ 1 + ω τ
For a passive material we must have ˜ < 0, which requires s > ∞ . It is straightforward
to show that these expressions obey the Kronig–Kramers relationships. The details are
left as an exercise.
A plot of the Debye spectrum of water at T = 20 C is shown in Figure 4.5, where we
◦
have used s = 78.3 0 , ∞ = 5 0 , and τ = 9.6 × 10 −12 s [49]. We see that ˜ decreases
over the entire frequency range. The frequency dependence of the imaginary part of the
permittivity is similar to that found in the resonance model, forming a curve which peaks
at the critical frequency
ωmax = 1/τ
where it obtains a maximum value of
s − ∞
−˜ max = .
2
At this point ˜ achieves the average value of s and ∞ :
s + ∞
(ωmax ) = .
2
Since the frequency label is logarithmic, we see that the peak is far broader than that
for the resonance model.
Interestingly, a plot of −˜ versus ˜ traces outa semicircle centered along the real axis
at ( s + ∞ )/2 and with radius ( s − ∞ )/2. Such a plot, shown in Figure 4.6, was first
described by K.S. Cole and R.H. Cole [38] and is thus called a Cole–Cole diagram or “arc
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