Page 14 - Bruno Linder Elementary Physical Chemistry

August 19, 2010 10:36 9in x 6in b985-fm Elementary Physical Chemistry

Contents xiii

10.5. Bond Order . .. .. ... .. .. ... .. .. ... .. 111
10.6. Polar Covalent Molecules . . . . . . . . . . . . . . . . 112
10.7. Structure of Polyatomic Molecules . . . . . . . . . . . 113
10.8. Normalization. Normal Constants . . . . . . . . . . . . 113
10.9. Normalization Molecules (MO) . . . . . . . . . . . . . 113

11. Elements of Molecular Spectroscopy 115
11.1. Vibration–Rotation Spectra of Diatomic Molecules . . 115
11.2. Rotational Selection Rules .. .. ... .. .. ... .. 115
11.3. Vibrational Selection Rules . . . . . . . . . . . . . . . 116
11.4. Further Requirements . . . . . . . . . . . . . . . . . . 116
11.5. Pure Rotational Spectra . . . . . . . . . . . . . . . . . 117
11.6. Vibration–Rotation Spectra . . . . . . . . . . . . . . . 117

12. Elements of Intermolecular Forces 120
12.1. Types of Intermolecular Forces . . . . . . . . . . . . . 120
12.1.1. Electrostatic Forces . . . . . . . . . . . . . . . 120
12.1.2. van der Waals Forces . . . . . . . . . . . . . . 121
12.2. Hydrogen Bonding . . . . . . . . . . . . . . . . . . . . 122
12.3. Intermolecular Forces and Liquid Properties . . . . . . 123
12.4. Properties of Liquids . . . . . . . . . . . . . . . . . . . 124
12.5. Classification of Solids by Types of Intermolecular
Forces . ... .. .. ... .. .. ... .. .. ... .. 125

Appendix A: Homework Problem Sets 127
Problem Set I. Chapter 1 .. .. ... .. .. ... .. 127
Problem Set II. Chapter 2 . .. .. . .. .. .. . .. . 128
Problem Set III. Chapters 3, 4, 5 ... .. .. ... .. 129
Problem Set IV. Chapter 6 . .. ... .. .. ... .. 130
Problem Set V. Chapter 7 .. .. ... .. .. ... .. 132
Problem Set VI. Chapters 8, 9 .. ... .. .. ... .. 134
Problem Set VII. Chapters 10, 11, 12 . . . . . . . . . . 135

Appendix B: Thermodynamic Data 137

Appendix C: Standard Reduction Potentials 139

Index 141