Page 158 - Bruno Linder Elementary Physical Chemistry

August 18, 2010 11:38 9in x 6in b985-index Elementary Physical Chemistry

Index 143

photon, 85, 88, 89, 103, 134 temperature, 1–4, 6, 7, 9, 12, 14,
polar bond, 123 17–19, 21–25, 27–30, 34, 38, 41,
polarizability, 122 43–45, 49, 51, 69, 70, 83–85, 94,
probabilistic, deterministic, 93 117, 121–123, 127–133, 136
promotion, 104, 108 theory, 5, 8, 9, 70–72, 82–86, 88–91,
93, 94, 97, 104, 105, 108, 136
R-branch, 118 activated complex, 70, 72, 73
Raoult’s Law, 46–48, 53 covalent, 104, 112, 125, 126
rotational constant, 115, 136 molecular orbital (MO), 104,
rotational spectroscopy, 82 108, 109, 113
Rydberg constant, 88, 98 thermodynamics, 6, 11, 12, 15, 20, 21,
29, 38, 43, 51, 56, 57, 60, 82, 137
Schr¨odinger, 82, 90, 92–95, 97, 98, First law, 11, 15, 16, 20, 21, 30
102, 105 Second law, 21, 30
solution, 4, 28, 38, 46–49, 51–53, 59, Third law, 29, 30
66, 67, 70, 74, 81, 92, 96–99, 101, Torr, 3, 38, 48, 49, 131
102, 106, 108, 110, 112, 120, 123, triple point, 43, 44
128, 130, 131
ideal, 2, 3, 5, 6, 9–11, 14, 18, 24, uncertainty principle, 82, 93, 95
27, 28, 37, 38, 41, 45–48, 56, unimolecular reaction, 74, 77, 78
120, 131
ideal dilute, 47, 48, 131 valence bond, 104–108
solute, 46–49, 51, 52, 131 van der Waals, 10, 121–123, 128
solvent, 20, 46–49, 52, 53, 131 VSEPR (Valence Shell Electron Pair
solvent chemical potential, 49 Repulsion), 104
spin, 101, 103, 106, 109
standard enthalpy, 18, 19, 30, 36, 55, work, 11–18, 22–24, 32, 34, 35, 37, 57,
56, 128, 129, 132, 137 59, 91, 135
standard Gibbs free energy, 129, 130 PV-work, 12, 17, 18, 32, 34, 35,
state function, 16, 17, 21, 28, 32, 34, 37, 45, 57, 58, 129
42, 58 work function, 85, 135
subshell, 99, 100, 135
surrounding, 12–15, 22, 23, 31–35, 129