Page 156 - Bruno Linder Elementary Physical Chemistry
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August 18, 2010 11:38 9in x 6in b985-index Elementary Physical Chemistry
Index
activated complex, 70, 72, 73 chain reaction, 79, 134
angular momentum, 88, 89, 99, 101, rates, 60–62, 66, 67, 69–72,
103 75–77, 80, 133, 134
anti-bonding orbital, 109, 111, 113 chemical kinetics, 60
approximation Clapeyron, 44, 46
Born–Oppenheimer, 105 Claussius–Clapeyron, 46
orbital, 109 colligative properties, 49
steady-state, 74, 80, 81 constant
Arrhenius equation, 69, 73 Boltzmann, 7, 31, 85
atomic radius, 103 de Broglie, 89, 90, 95, 135
Debye, 85, 90
Balmer, 89, 135 depression, 49–51
bar, 3, 6, 18, 30, 37, 127 elevation, 49–52, 131
black-body radiation, 83, 84 equilibrium, 2, 14, 21, 29, 34, 35,
Bohr, Niels, 88, 89, 91–93, 96 40, 41, 43, 45, 46, 51, 53, 55,
Bohr radius, 96 56, 58–60, 70, 72–74, 76, 77,
boiling point, 49–52, 123, 125, 129, 80, 81, 117, 129, 130, 132
131, 136 gravitational, 12, 13, 127, 128
boiling temperature, 51, 136 Henry’s Law, 47, 48, 130, 131
bond normalization, 113, 114
σ and π, 104 Planck, 22, 73, 84, 85, 88, 134
chemical, 104 reaction rate, 60–62, 66, 67,
covalent, 104, 112, 125, 126 69–72, 75–77, 80, 133, 134
ionic, 104, 126 Rydberg, 88, 98
length, 117, 136 Copenhagen Interpretation, 93, 95
order, 111, 112
polar, 112, 120–123 degenerate, 102, 103, 110
valence, 104–108 delocalized, 113, 126
Born, 82, 90–92, 105 diatomic molecule, 111, 112, 114–116,
Born–Oppenheimer approx, 105 122
diffusion, 8–10
Carnot cycle, 22, 23, 25, 26 dipole–dipole interaction, 121
cathode, 57 dipole moment, 29, 117, 120–122
141