Page 157 - Bruno Linder Elementary Physical Chemistry

August 18, 2010 11:38 9in x 6in b985-index Elementary Physical Chemistry

142 Elementary Physical Chemistry

dispersion interaction, 122 heat, 2, 11, 12, 14–23, 25–27, 29, 32,
Dulong and Petit, 85 34, 83–85, 94, 128, 129
heat capacity, 14, 15, 18, 19, 29, 83,
Einstein, Albert, 84, 85, 89, 93 85, 128, 129
electrode, 58 Heisenberg, Werner, 90, 91, 93
electromagnetic radiation, 82, 83, 86, Henry’s Law, 47, 48, 130, 131
88 Hund’s Rule, 103, 109
electronegativity, 112 hybrid orbital, 108
energy hydrogen bonding, 122, 123, 125
as heat, 2, 11, 12, 14–23, 25–27, hydrogenic atom, 98–100, 102
29, 32, 34, 83–85, 94, 128, 129
hydrogen, 99, 105, 109 induction forces, 121–123
internal energy, 11, 15, 17, 39 interaction, 10, 120, 121, 124
dipole–dipole, 121
photon, 85, 88, 89, 103, 134
dipole–induced dipole, 121
energy level, 30, 31, 82, 88, 91, 92, 97,
van der Waals, 10, 121–123, 128
102, 109, 112, 115, 117, 136
dispersion, 122
enthalphy, 128–132
internal energy, 11, 15, 17, 39
entropy, 21, 129
isolated system, 21, 27, 32, 33
equation
Arrhenius, 69, 73
Joule–Thomson, 10
Schr¨odinger, 82, 90, 92–95, 97,
98, 102, 105
kinetic energy, 7, 11, 71, 85, 135
van der Waals, 10, 128
virial, 10, 128
Lindemann mechanism, 77
equation of state, 2, 3, 10, 122, 128
Lyman Series, 89, 101
perfect gas, 3
van der Waals, 122 molality, 51
moment of inertia, 115, 117, 119, 136
First Law, 11, 15, 16, 20, 21, 30
formation Newton, Isaac, 83
bond, 105, 106 nonpolar molecules, 121–123
Gibbs free energy, 129
rate of, 61, 63, 67, 73, 75, 132 orbital, 82, 88, 99, 100, 102–113, 136
standard enthalpy, 18, 19, 30, hybrid, 108, 113
36, 55, 56, 128, 129, 132, 137 moelecular, 104, 108, 109, 113,
freezing point, 49–51, 131 136
osmotic pressure, 49, 52, 53, 131
Gibbs free energy, 33, 34, 38, 39, 58,
129, 130 P-branch, 118
and equilibrium constant, 35, 40, partial molar Gibbs energy, 39
41, 55, 56, 59, 73, 77, 129, pascal, 2, 4
130, 132 Paschen Series, 89, 135
Pauli, Wolfgang, 102, 103
half-reaction, 57 phase rule, 43, 44
harmonic oscillator energy, 85, 91, 116 photoelectric effect, 83–86