Page 184 - Elements of Chemical Reaction Engineering 3rd Edition
P. 184

1 56                                  Isothermal Reactor Design   Chap. 4







                         Simplifying yields


                                                                                      (4-24)

                                               1                      I
                         where


                                                                                      (4-25)


                              For tubular packed-bed reactors we are more interested in catalyst weight
                         rather than  the distance z down the reactor. The catalyst weight up  to  a dis-
                         tance of z down the reactor is

                                        W       =    (1 -+)A,z    X        Pc

                                     weight of       volume of          density of
                                    [ catalyst ]  =  [  solids        [sdidcatalys~  (4-26)

                         where A,  is the cross-sectional area. Tbe bulk density of the catdyst,  pb  (mass
                         of catalyst per volume of  reactor bed), is just the product of  the solid density,
                         pc , the fraction of solids, (1 - $) :
                                                    Pb = pc (l - 4)

                              Using the relationship between z and W [Equation (4-26)] we can change
                         our variables to express the Ergun equation in terms of catalyst weight:
          Use this form for
          multiple reactions                dP
            and membrane                                                              (4-27)
                 reactors

                         Further simplification yields
     Lety=P/Po
                                                                                      (4-28)



                         where

                                                                                      (4-29)
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