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152                            Enhanced Oil Recovery in Shale and Tight Reservoirs


          recovery factor was 0.515, indicating not much oil produced after the
          breakthrough.
             One may think that water preferentially invades into smaller pores, as the
          capillary pressure as a driving force is higher. However, the resistance in
          smaller pores is also higher. As a result, water imbibition velocity is higher
          in large pores (Sheng, 2017c). This can be explained as follows.
             Based on Poiseuille’s law, Washburn (1921) derived an equation to
          describe the imbibition velocity in a single capillary tube. The velocity equa-
          tion can be restated as follows without including the coefficient of slip or a
          noncapillary drive force:

                                    dl   s cos q
                                       ¼       r                       (7.1)
                                    dt    4m l
                                            w
             In the Eq 7.1, l is the imbibition distance, t is the imbibition time, s is the
          interfacial tension, m w is the wetting phase viscosity, q is the contact angle,
          and r is the capillary radius. We can see that the imbibition velocity into a
          larger pore is lower than that into a smaller pore. A small radius corresponds
                                                            p ffiffiffiffiffiffiffiffi
          to a low permeability reservoir because r is proportional to k=4. Now we
          can understand that in the low-permeability rock, although the capillary
          force is higher, the viscous force is high as well; by considering these two
          forces, the imbibition velocity in the low-permeability rock is actually lower
          than that in the high-permeability rock. Note that the above ignores the slip
          flow. For the slip flow to take place, the capillary diameter needs to be
          smaller than approximately 3 nm (Sharp et al., 2001). This was confirmed
          by an experimental and theoretical study by Koo and Kleinstreuer (2003).
          Thus, the continuum theory is still applicable to fluid flow through nano-
          pores in shale matrix in a practical sense.
             The above theory is consistent with what was observed by Lin et al.
          (2016) as shown in Fig. 7.1. This figure also shows that when there was a
          fracture, the water could much more quickly imbibe into the neighbor ma-
          trix. Another important mechanism is the imbibed water increase reservoir
          pressure and local pressure so that the drive energy is boosted. From the
          imbibition point of view, water-wet formation is preferred. This conclusion
          is supported by experimental data by Huang and Xiang (2004). By the way,
          Sun et al. (2015) attributed their slower imbibition rate after the cores
          were dried in an oven to the fractures generated during the earlier water
          imbibition. They argued that the existence of fractures with openings in mi-
          crometers reduced capillary pressure; thus the imbibition rate was decreased.
          As discussed here, the resistance in fractures is lower and the resulting
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