Page 184 - Entrophy Analysis in Thermal Engineering Systems
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Exergy                                                       179


              power-generating systems. It reveals that the efficiency of a Carnot cycle
              constrained to operate between the same highest and lowest temperatures
              of a combustion-driven cycle is not an accurate efficiency bound.
                 Based on this argument, it would be inappropriate to define the second
              law efficiency of a heat engine as the ratio of the actual thermal efficiency (η a )
              to the efficiency of the corresponding Carnot engine. It should rather be
              defined as the ratio of η a to η max . Hence,
                                                η
                                         η   ¼   a                      (11.35)
                                          SL   η
                                                max
              The second law efficiency defined in Eq. (11.35) accounts for the heat
              source type because as discussed, the maximum theoretical work production
              of a heat engine may vary depending on whether the thermal energy
              requirement of the engine is supplied from thermal reservoir(s), hot
              stream(s), or fuel.



                   11.7 Minimum exhaust temperature
                   According to the second law, a portion of the thermal energy supplied
              to a heat engine must be rejected to the surroundings, even at fully reversible
              operation where entropy generation is zero. From this principle, we may
              define a minimum exhaust temperature for an engine that is run by a hot
              stream or fuel combustion. In this case, the amount of heat rejected by
              the engine is obtained using Eq. (11.12). If the heat is supplied by a hot
              stream (Fig. 11.2A), the heat rejected at the reversible limit can also be deter-
              mined by

                                rev
                                                 fl
                              Q ¼ H  H 0 Þ Ψ ¼ T 0 S  S 0 Þ             (11.36)
                                                      ð
                                    ð
                                e
              Comparing Eq. (11.12) with Eq. (11.36), one obtains
                                    H  H 0 ¼ T 0 S  S 0 Þ               (11.37)
                                                 ð
                                      rev
                                     e
              Notice that H e denotes the enthalpy of the hot stream at the engine exit, and
              S is the entropy of the stream at the inlet of the engine. Assume that the hot
              steam is an ideal gas with a uniform pressure. The minimum exhaust tem-
              perature or the exhaust temperature at reversible operation may be deter-
              mined by

                                        ¼ T 0 1+ ln                     (11.38)
                                      rev           T
                                    T
                                     e
                                                    T 0
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