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Exergy                                                       177




                   11.6 Maximum efficiency

                   The maximum thermal efficiency of a heat engine is defined as the
              maximum theoretical work per unit thermal energy supplied to the engine.
              The form of expression for the engine efficiency depends on whether heat is
              supplied from a thermal reservoir, a hot stream, or fuel. The relations that we
              derived for maximum work in Sections 11.2–11.4 will now be used to
              derive expressions for the maximum efficiency of a heat engine.
                 For an engine, which receives a given quantity of heat from p thermal
              reservoirs while communicating with n+1 reservoirs (Fig. 11.1), dividing
              the maximum work obtained from Eq. (11.9) with Ψ de ¼0 by the total
              amount of heat imparted to the engine yields


                                          p
                                                   n
                                         X        X
                                            Ψ         Ψ th
                                              th
                                              j         k
                                         j¼1     k¼p +1
                                   η   ¼                                (11.30)
                                    max        p
                                              X
                                              j¼1  Q j
              In the simplest case with two thermal reservoirs (n¼1 and p¼1), Eq. (11.30)
              reduces to the Carnot efficiency.


                                               T 0
                                     Ψ th  1       Q 1
                              η   ¼   1  ¼     T 1    ¼ 1   T 0         (11.31)
                               max
                                     Q 1      Q 1          T 1
              If the engine, as another example, receives a given quantity of Q 1 +Q 2 heat
              from two thermal reservoirs (p¼2) and rejects heat to only one reservoir
              (n¼2), we have
                                 2

                                   Ψ th       T 0          T 0
                                X
                                          1       Q 1 +1
                                     j                         Q 2
                          η   ¼  j¼1   ¼      T 1          T 2          (11.32)
                           max    2
                                X                 Q 1 + Q 2
                                 j¼1  Q j
              The expression for the maximum efficiency of an engine that receives heat
              from a hot stream obeys
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