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                       Fracture Mechanisms in Nonmetals                                            271


                          Composite materials usually consist of a matrix and a reinforcing constituent. The matrix is often
                       soft and ductile compared to the reinforcement, but this is not always the case (see Section 6.2).
                       Various types of reinforcement are possible, including continuous fibers, chopped fibers, whiskers,
                       flakes, and particulates [20].
                          When a polymer matrix is combined with a strong, high-modulus reinforcement, the resulting
                       material can have superior strength/weight and stiffness/weight ratios compared to steel and
                       aluminum. Continuous fiber-reinforced plastics tend to give the best overall performance (com-
                       pared to other types of polymer composites), but can also exhibit troubling fracture and damage
                       behavior. Consequently, these materials have been the subject of extensive research over the past
                       40 years.
                          A variety of fiber-reinforced polymer composites are commercially available. The matrix material
                       is usually a thermoset polymer (i.e., an epoxy), although thermoplastic composites have become
                       increasingly popular in recent years. Two of the most common fiber materials are carbon, in the
                                                                                5
                       form of graphite, and aramid (also known by the trade name, Kevlar),  which is a high-modulus
                       polymer. Polymers reinforced by continuous graphite or Kevlar fibers are intended for high-
                       performance applications such as fighter planes, while  fiberglass is an example of a polymer
                       composite that appears in more down-to-earth applications. The latter material consists of randomly
                       oriented chopped glass fibers in a thermoset matrix.
                          Figure 6.14 illustrates the structure of a fiber-reinforced composite. Consider a single ply
                       (Figure 6.14(a)). The material has high strength and stiffness in the fiber direction, but has relatively
                       poor mechanical properties when loaded transverse to the fibers. In the latter case, the strength and
                       stiffness are controlled by the properties of the matrix. When the composite is subject to biaxial
                       loading, several plies with differing fiber orientations can be bonded to form a laminated composite
                       (Figure 6.14(b)). The individual plies interact to produce complex elastic properties in the laminate.
                       The desired elastic response can be achieved through the appropriate choice of the fiber and matrix
                       material, the fiber volume, and the lay-up sequence of the plies. The fundamentals of orthotropic
                       elasticity and laminate theory are well established [21].

                       6.1.3.1 Overview of Failure Mechanisms

                       Many have attempted to apply fracture mechanics to fiber-reinforced composites, and have met
                       with mixed success. Conventional fracture mechanics methodology assumes a single dominant
                       crack that grows in a self-similar fashion, i.e., the crack increases in size (either through stable or
                       unstable growth), but its shape and orientation remain the same. Fracture of a fiber-reinforced
                       composite, however, is often controlled by numerous microcracks distributed throughout the mate-
                       rial, rather than a single macroscopic crack.  There are situations where fracture mechanics is
                       appropriate for composites, but it is important to recognize the limitations of theories that were
                       intended for homogeneous materials.
                          Figure 6.15 illustrates various failure mechanisms in fiber-reinforced composites. One advan-
                       tage of composite materials is that fracture seldom occurs catastrophically without warning, but
                       tends to be progressive, with subcritical damage widely dispersed through the material. Tensile
                       loading (Figure 6.15 (a)) can produce matrix cracking, fiber bridging, fiber rupture, fiber pullout,
                       and fiber/matrix debonding. Ultimate tensile failure of a fiber-reinforced composite often involves
                       several of these mechanisms. Out-of-plane stresses can lead to delamination (Figure 6.15 (b))
                       because the fibers do not contribute significantly to the strength in this direction. Compressive
                       loading can produce the microbuckling of fibers (Figure 6.15(c)); since the polymer matrix is
                       soft compared to the fibers, the fibers are unstable in compression. Compressive loading can also
                       lead to macroscopic delamination buckling (Figure 6.15(d)), particularly if the material contains
                       a preexisting delaminated region.

                       5  Kevlar is a trademark of the E.I. Dupont Company.
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