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44    INTRODUCING LANDFORMS AND LANDSCAPES


                                                       a
              Table 2.4 Average composition of river waters by continents (mg/l)
              Continent     SiO 2   Ca 2+   Mg 2+    Na +   K +    Cl –   SO 4 2–  HCO 3 –   i b

              Africa        12.0     5.25   2.15    3.8     1.4    3.35    3.15   26.7       45.8
              North America  7.2    20.1    4.9     6.45    1.5    7.0    14.9    71.4      126.3
              South America  10.3    6.3    1.4     3.3     1.0    4.1     3.5    24.4       44.0
              Asia          11.0    16.6    4.3     6.6     1.55   7.6     9.7    66.2      112.5
              Europe         6.8    24.2    5.2     3.15    1.05   4.65   15.1    80.1      133.5
              Oceania       16.3    15.0    3.8     7.0     1.05   5.9     6.5    65.1      104.5
              World         10.4    13.4    3.35    5.15    1.3    5.75   8.25    52.0       89.2
              Notes:
              a  The concentrations are exoreic runoff with human inputs deducted
              b   i is the sum of the other materials
              Source: Adapted from Meybeck (1979)


                 and sodium, which are determined primarily by  river runoff (itself related to climatic factors) and then on
                 evaporation and fractional crystallization and which  lithology.
                 are exemplified by the Rio Grande and Pecos
                 rivers.
                                                        Regional and global patterns of
                                                        denudation
              This classification has been the subject of much debate
              (see Berner and Berner 1987, 197–205), but it seems  Enormous variations in sediment and solute loads of
              undeniable that climate does have a role in determining  rivers occur within particular regions owing to the local
              the composition of river water, a fact borne out by the  effects of rock type, vegetation cover, and so forth.
              origin of solutes entering the oceans. Chemical erosion is  Attempts to account for regional variations of denuda-
              greatest in mountainous regions of humid temperate and  tion have met with more success than attempts to explain
              tropical zones. Consequently, most of the dissolved ionic  global patterns, largely because coverage of measuring
              load going into the oceans originates from mountainous  stations is better and it is easier to take factors other than
              areas, while 74 per cent of silica comes from the tropical  climate into consideration. Positive correlations between
              zone alone.                               suspended sediment yields and mean annual rainfall and
                Further work has clarified the association between  mean annual runoff have been established for drainage
              chemical weathering, mechanical weathering, lithology,  basins in all parts of the world, and simply demon-
              and climate (Meybeck 1987). Chemical transport, mea-  strate the fact that the more water that enters the system,
              sured as the sum of major ions plus dissolved silica,  the greater the erosivity. Solute loads, like suspended
              increases with increasing specific runoff, but the load  sediment loads, exhibit striking local variations about
              for a given runoff depends on underlying rock type  the global trend. The effects of rock type in particu-
              (Figure 2.5). Individual solutes show a similar pat-  lar become far more pronounced in smaller regions. For
              tern. Dissolved silica is interesting because, though the  example, dissolved loads in Great Britain range from 10
                                                                         2
              rate of increase with increasing specific discharge is  to more than 200 t/km /yr, and the national pattern is
              roughly the same in all climates, the actual amount  influenced far more by lithology than by the amount
              of dissolved silica increases with increasing tempera-  of annual runoff (Walling and Webb 1986). Very high
              ture (Figure 2.5b). This situation suggests that, although  solute loads are associated with outcrops of soluble rocks.
                                                                                          2
              lithology, distance to the ocean, and climate all affect  An exceedingly high solute load of 6,000 t/km /yr has
              solute concentration in rivers, transport rates, especially  been recorded in the River Cana, which drains an area of
                                                                                             2
              in the major rivers, depend first and foremost on specific  halite deposits in Amazonia; and a load of 750 t/km /yr
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