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Vacuum and Tritium System  Chapter | 6    205


             pumping system structure and geometry optimisation, spacecraft ambient air
             modelling, and so on.
                An original concept summarised later allows removing these restrictions. It
             is based on a set of differential and integral characteristics of a vacuum system.
                The differential characteristics include the statistically determined molecule–
             surface interaction parameters (e.g. the accommodation, reflection, sticking,
             condensation and stimulated gas release coefficients) and local characteristics
             (such as the molecular concentration and incident molecular flow density).
                The integral characteristics describe the molecular continuum interaction
             with certain surfaces. The key integral characteristics are the followings:

             l  The capture coefficient of a sorbent, such as a vacuum surface-action pump.
             l  The return coefficient reflecting the possibility of return to the VS ‘area of
                departure’ for a population of molecules.
                These characteristics allow the construction of a closed system of equations
             describing, unconditionally, a rarefied gas behaviour.
                An integral method of kinetic analysis, developed as an extension of the
             concept presented, is premised on using the integral form of the kinetic equa-
             tion. The components in the right side of the equation describe
             l  thermal desorption/diffusion flows coming through the vacuum chamber wall,
             l  gas flows from local in-chamber sources, and
             l  integral flows of molecules reflected by the surface, and molecules emitted
                by the surface as a result of stimulated desorption.
                The resultant integral equation for the density of a molecular flow hitting an
             elemental site inside the chamber is the basis for determining the characteristics
             of a system under analysis. Assuming that the latter has m surfaces with deter-
             mined parameters, we can take the range of integration as a composition of m
             parts and transform the initial integral equation into a linear algebraic system of
             equations. Equation coefficients and ‘elemental’ molecular concentration values
             under assumed diffuse and isotropic scattering of molecules by the walls have
             been computed for typical geometrical structures.
                Any structural or geometrical complication of a VS design quickly leads to
             a computational intractability. This problem can be circumvented by using the
             equivalent surface method, which is a logical model and a computational algo-
             rithm for estimating molecular flows in multi-component vacuum system, and
             for their design optimisation.
                This method implies that actual components of a system under design are
             substituted by simply shaped gas-kinetic equivalents.  These equivalents are
             attributed characteristics that are inferred from the identity of the actual system
             and its model’s molecular characteristics. For example, a sorbent’s inlet cross
             section is taken to be the sorbent’s equivalent surface. The latter is attributed
             the ability of ‘interacting’ with molecular flows, which the substituted sorbent
             possesses. A characteristic attributed with respect to a chamber to be evacuated
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