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Vacuum and Tritium System  Chapter | 6    207



               TABLE 6.7 Parameters of Interaction Between a Molecule and a Sorbing
               Surface

                                                                 Factors
                                                                 determining
                                                                 the elemental
                                        Active
               Gas         Elemental    centre                   interaction
               absorption   interaction   physical   Coefficients  parameter
               mechanism   parameter    analogue  η   ϑ
               Sorption by   Number of   χ  Deposited   χ −1     Getter layer
               a constantly   deposited   getter                 thickness
               renewable   getter atoms   atoms
               getter film  per one gas
                           molecule
               Condensation  Condensa-  β  Set of   β  1.0       Condensate
                           tion         points on a              layer thickness
                           coefficient  cryosurface
               Adsorption  Sticking    β  Adsorption   1.0  Relative   Adsorbate
                           coefficient  centres       concentration  surface
                                                      of adsorption   concentration
                                                      centres
               Chemisorption  Chemical   β  Sorption   1.0  Relative   Adsorbate
                           bond         centres       concentration  volume
                           formation                  of sorption   concentration
                           probability                centres
               Implantation  Implantation  µ  The same  µ  1.0   Density of
                           coefficient                           implanted
                                                                 particles




             geometrically more complex device that has adsorbing surfaces, any part of
             which is able to maintain a minimum flow of active centres necessary for the
             pumped-out gas absorption, is believed to be an optimum design solution.
                Thus, the optimisation design methods must be based on a quantitative esti-
             mate of the degree to which the designed structure approaches its optimum the-
             oretical model. The independent or controlled external factors can in this case
             be the 3D flow distribution of the removed gas, the geometrical structure of the
             surface-action pump and the vacuum duct as a whole, as well as characteristics
             of the sorbing surfaces (Table 6.8).
                The term ‘useful work’ in Table 6.8 refers to any physical parameter char-
             acterising the high-vacuum system’s purpose and operation requirements.
             Optimisation of a vacuum pumping duct implies, among other things, the use of
             a differential pumping, localisation of elevated molecular concentration regions,
             and creation of a network of channels for high-density gas flows.
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