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                                                                            THE ROLE OF VOLATILES  71


                                                              way nucleation proceeds depends on the avail-
                                                              ability of sites for nucleation and the degree of
                                                              supersaturation of the magma at any given time.
                                                              Nevertheless, in general the magma will contain
                                                              some relatively large bubbles that formed some
                                                              time ago at deeper levels beneath the surface and
                                                              which have been growing through diffusion and
                                                              decompression, and also some very small bubbles
                                                              which have just formed. A spectrum of bubble sizes
                                                              will exist between these two extremes (Fig. 5.6).
                                                                All of these bubbles are rising relative to the
                                                              magma because of their buoyancy but the larger
                                                              bubbles are rising faster than the smaller ones
                                                              (eqn 5.12). This means that the larger bubbles can
                                                              overtake the slower, smaller bubbles. When this
                                                              happens there are two possibilities. The small bub-
                                                              ble may be swept around the larger one, effectively
                                                              trapped in the liquid magma moving sideways and
                                                              down to let the larger bubble pass, and thus may be
                                                              left behind as the large bubble continues to move
                                                              upward. But if the small bubble is close enough to
                                                              the large one it may be swept into the wake of
                                                              the large bubble. This wake consists of some liquid
                                                              magma that is effectively trapped behind the large
                                                              bubble and is moving up with it through the rest of
                                                              the liquid. The small bubble is no longer left behind
                                                              but instead rises slowly through the wake liquid
                                                              and eventually collides with the bottom of the large
                 Fig. 5.6 The typical distribution of bubble sizes within
                 magma rising toward the surface. The largest bubbles are  bubble and coalesces with it, forming a single, lar-
                 those that formed earliest at the greatest depth beneath the  ger bubble. This new, larger bubble then rises even

                 surface and have grown by diffusion and decompression;  faster, overtakes more bubbles and coalesces with
                 the smallest bubbles are those that have most recently  some of them, growing larger and moving even
                 nucleated. The length of the arrows extending from each
                                                              faster and so on. This runaway process can lead to a
                 bubble reflects the relative rise speeds of the bubbles
                                                              situation where a single large bubble (called a slug)
                 through the magma, largest bubbles having the greatest
                                                              can fill the whole width of the dike or conduit,
                 rise speeds.
                                                              absorbing all of the smaller bubbles ahead of it as it
                                                              continues to rise.
                 rises by nearly twice its own diameter in one sec-  In basaltic magmas, a critical factor in determin-
                 ond in the basalt but by only about one-twentieth   ing whether bubble coalescence can occur is the
                 of one percent of its own diameter in the rhyolite.  rise speed of the magma. A simple example will
                   Figure 5.6 shows schematically what might be  illustrate why this is the case. Consider magma
                 seen if a “snapshot” could be taken of the bubbles  rising over a distance of 500 m. If the rise speed of
                 within magma which is rising towards the surface.  the magma is 1 m s −1  then it takes 500 seconds for
                 At any given time the magma will contain a popu-  the magma to rise 500 m. If the magma rise speed is
                                                                        −1
                 lation of bubbles of various sizes. Once bubbles  only 0.1 m s then it takes 5000 seconds to move
                 start to form at the  exsolution level, new bub-  the same distance. If a bubble in the magma is rising
                                                                                                 −1
                 bles continue to nucleate until the magma is finally  relative to the magma at a speed of 0.01 m s then
                 erupted. However, as was seen earlier, the exact  in 500 seconds it will rise a distance of 5 m through
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