Page 187 - Gas Purification 5E
P. 187

174    Gas Purification

                   and Condit (1952) in which MEA is added to the caustic prewash upstream of an extractive
                   Meros unit to achieve COS removal. According to Johnson and Condit, the MEA concentra-
                   tion in the caustic must be maintained at about 1.5 wt% or higher to achieve nearly complete
                   COS removal (~0.04 ppmw COS reported as S). The caustic concentration must be pater
                   than 3.0 wt% for the reaction to occur, and the volumetric ratio of the formulated caustic to
                   the LPG flow should be  10: 1. When both MEA and caustic are. present, the MEA is not con-
                   sumed by reaction with the COS.




                   Abe, T., and Peterzan, P., 1980, Oil and GasJ., March 31, p. 139.
                   AI-Ghawas. H. A., Ruiz-Ibanez, G., and Sandall, 0. C.,  1988, “Absorption of Carbonyl Sul-
                     fide  in Aqueous Methyldiethanolamine,” presented at the Spring National Meeting of the
                     AIChE, New Orleans, LA, March 1-10.
                   Ammom, H. L., and Sitton, D. M., 1981, ;‘Operating Data from a Commercial MDEA Treater,“
                     Proceedings of the 1981 Gas Conditioning Conzrence, University of Oklahoma, OK.
                   Anon.,  1946, Petrol. R.$ner,  Vol. 25, No. 10, p.121.
                   Anon.,  1981, Chein. & Eng. Nm~s, Sept. 7, p. 58.
                   Appl, M.,  Wagner, U.,  Henrici, H. J.,  Kuessner, K.,  Volkamer, K.,  and Fuerst, E.,  1980,
                     “Removal of  COz and/or H2S and/or COS from gases containing these constituents,”
                     Canadian Patent No. 1,090,098.
                   Arnold, D. S., Barrett, D. A., and Isom, E. H., 1982. “CO,  Can Be Produced from Flue Gas,”
                     Oil & Gas J., Nov. 22, p. 130.
                   Astarita, G., 1967, ilrlass Transfer with Chemical Reaction, Elsevier, Amsterdam.
                   Astarita, G.,  Savage, C. W.,  and Basio, A.,  1983, Gas Treating with Chemical Solvents,
                     Wiley, N.Y.
                   Atadan, E. M.: 1954, “Absorption of Carbon Dioxide by Aqueous Monoethanolamine Solu-
                     tions,” Ph.D. thesis, University of Tennessee, Knoxville, TN.
                   Atwood, K., Arnold? M. R., and Kindrich, R. C., 1957, hid. Eng. Chem.. Vol. 49, September,
                     p. 1439.
                   Austgen, D. M., Rochelle, G. T.,  and Chen, C. -C.,  1991, “Model of Vapor-Liquid Equilibria
                     for Aqueous Acid Gas-Abnolamine Systems,” 2. “Representation of H2S and COz Solu-
                     bility in Aqueous MDEA and C02 Solubility in Aqueous Mixtures of MDEA with MEA
                     or DEA,“ Znd. Eng. Chern. Res., Vol. 30, p. 543.
                   Bacon, K.  H..  1972, “Liquid Treating,”  Proceedings of  the  Gas Conditioning Conference,
                     University of Oklahoma, Norman, OK.
                   Bacon, T. R., and Pearce, R. L., 1985, “Energy Conservation and H2S Selectivity With COS
                     Removal,“ paper presented at Pem Energy ’85, Sept. 16-20.
                   Bailleul, M., 1969: Gas Processing Canada, Vol. 61, No. 3, pp. 34-38.
                   Bally, A. P.,  1961, Erdol und Kohle, Vol. 14, pp. 921-923.
                   Bartholome, E.,  Schmidt, H.  W.:  Friebe, J.,  1971, “Process for Removing Carbon Dioxide
                     from Gas Mixtures,” U.S. Patent 3,622,267.
                   Beddome, J. M.,  1969, “Current Natural Gas Sweetening Practice,” paper presented at 19th
                     Canadian Chemical Engineering Conference, October.
   182   183   184   185   186   187   188   189   190   191   192