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and Condit (1952) in which MEA is added to the caustic prewash upstream of an extractive
Meros unit to achieve COS removal. According to Johnson and Condit, the MEA concentra-
tion in the caustic must be maintained at about 1.5 wt% or higher to achieve nearly complete
COS removal (~0.04 ppmw COS reported as S). The caustic concentration must be pater
than 3.0 wt% for the reaction to occur, and the volumetric ratio of the formulated caustic to
the LPG flow should be 10: 1. When both MEA and caustic are. present, the MEA is not con-
sumed by reaction with the COS.
Abe, T., and Peterzan, P., 1980, Oil and GasJ., March 31, p. 139.
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AIChE, New Orleans, LA, March 1-10.
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Proceedings of the 1981 Gas Conditioning Conzrence, University of Oklahoma, OK.
Anon., 1946, Petrol. R.$ner, Vol. 25, No. 10, p.121.
Anon., 1981, Chein. & Eng. Nm~s, Sept. 7, p. 58.
Appl, M., Wagner, U., Henrici, H. J., Kuessner, K., Volkamer, K., and Fuerst, E., 1980,
“Removal of COz and/or H2S and/or COS from gases containing these constituents,”
Canadian Patent No. 1,090,098.
Arnold, D. S., Barrett, D. A., and Isom, E. H., 1982. “CO, Can Be Produced from Flue Gas,”
Oil & Gas J., Nov. 22, p. 130.
Astarita, G., 1967, ilrlass Transfer with Chemical Reaction, Elsevier, Amsterdam.
Astarita, G., Savage, C. W., and Basio, A., 1983, Gas Treating with Chemical Solvents,
Wiley, N.Y.
Atadan, E. M.: 1954, “Absorption of Carbon Dioxide by Aqueous Monoethanolamine Solu-
tions,” Ph.D. thesis, University of Tennessee, Knoxville, TN.
Atwood, K., Arnold? M. R., and Kindrich, R. C., 1957, hid. Eng. Chem.. Vol. 49, September,
p. 1439.
Austgen, D. M., Rochelle, G. T., and Chen, C. -C., 1991, “Model of Vapor-Liquid Equilibria
for Aqueous Acid Gas-Abnolamine Systems,” 2. “Representation of H2S and COz Solu-
bility in Aqueous MDEA and C02 Solubility in Aqueous Mixtures of MDEA with MEA
or DEA,“ Znd. Eng. Chern. Res., Vol. 30, p. 543.
Bacon, K. H.. 1972, “Liquid Treating,” Proceedings of the Gas Conditioning Conference,
University of Oklahoma, Norman, OK.
Bacon, T. R., and Pearce, R. L., 1985, “Energy Conservation and H2S Selectivity With COS
Removal,“ paper presented at Pem Energy ’85, Sept. 16-20.
Bailleul, M., 1969: Gas Processing Canada, Vol. 61, No. 3, pp. 34-38.
Bally, A. P., 1961, Erdol und Kohle, Vol. 14, pp. 921-923.
Bartholome, E., Schmidt, H. W.: Friebe, J., 1971, “Process for Removing Carbon Dioxide
from Gas Mixtures,” U.S. Patent 3,622,267.
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