Page 322 - gas transport in porous media
P. 322

Chapter 19: In Situ Measurement of Induced Flux
                                        Injection of                                       321
                                        clean gas                   Gas collection
                                                                              Surface
                                                                    and analysis
                                                              Probe
                                                              External Teflon tube
                                                              Inner Teflon tube



                                                   Gas
                                                              In Situ void
                                                   flux
                                                              Sacrificial tip
                                                                          Ground water
                                      COVERED BY US PATENTS

                                           Injection of
                                           clean gas                Gas collection
                                                                              Surface
                                                                    and analysis
                                                              Well
                                                              External Teflon tube
                                                              Inner Teflon tube

                                                                       Packers
                                                Gas
                                                flux
                                                                Soil formation
                                                                Permeable zone around well
                                                                           Groundwater
                                      COVERED BY US PATENTS
                           Figure 19.2.  Schematic of the In Situ flux method and associated equipment. Top: probe configuration.
                           Bottom: existing well configuration


                           to identify analytes that diffuse due to an artificial chemical gradient. We term this
                           flux “diffusive flux.” This process is shown schematically as Figure 19.3.
                             Using the same sampling event, the method has been further developed to mea-
                           sure in situ flux of biogenic gases (e.g., those produced during the degradation of
                           organic contaminants). When advective flux of daughter compounds within “active”
                           subsurface locations is superior to their in situ flux at “inactive” locations, production
                           rate is estimated. Basically, mapping of advective and diffusive flux of fluids are
                           used to evaluate whether the migration process is primarily controlled by advection,
                           diffusion, or production. An experimental setting is shown on Figure 19.2 to apply
                           the proposed sampling method in existing wells.
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