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Chapter 5: Two-Phase Gas Transport
                           Gas relative permeability
                                                             
                              61
                                                k r,g = (1 − S e ) 2  1 − S e (2+λ)/λ
                           van Genuchten (1976, 1980) presents Mualem-based expressions for the Brooks
                           and Corey liquid-phase relative permeability. A gas-phase expression could be sim-
                           ilarly derived. However, because these expressions have not been compared with
                           experimental data, they will not be presented here.
                             Figure 5.3 shows some generic Brooks and Corey two-phase characteristic curves.
                           Note that the Brooks and Corey capillary pressure does not go to zero as the liquid
                           saturation goes to 1.0. This behavior is expected because the straight-line fit does not
                           fit the data in this region (P c < P b ). In contrast, the van Genuchten capillary pressure
                           curve in Figure 5.1 does go to zero as the liquid saturation goes to 1.0. This behavior
                           at high liquid saturations is one reason why the van Genuchten characteristic curves
                           are much more popular than the Brooks and Corey formulation. The behavior of the
                           Brooks and Corey capillary pressure curve is similar to van Genuchten as the satura-
                           tion approaches the residual value. Note that Webb (2000) only discussed extension
                           of the van Genuchten capillary pressure curve, although the same procedure could
                           be applied to Brooks and Corey. The liquid-phase relative permeability increases
                           significantly as liquid saturation is increased, similar to van Genuchten–Mualem
                           shown earlier. The gas-phase relative permeability decreases with increasing liquid
                           saturation and is concave up. The shape of the curve is opposite of the van Genuchten–
                           Mualem curves (Parker et al., 1987; Luckner et al, 1989 extensions) shown earlier.
                           Note that Brooks and Corey (1964, 1966) present data-model comparisons for the
                           capillary pressure as well as the wetting (liquid) and non-wetting (gas) relative perme-
                           abilities, which show good results for all relationships including non-wetting relative
                           permeability. The two van Genuchten–Mualem relationships have not been compared
                           to data.
                             The range of the Brooks and Corey parameters for the nine soils investigated by
                           Brooks and Corey (1966) are P b from 14 to 75 cm (1400 to 7500 Pa), λ from 1.8 to
                           7.3, and S  ,r from 0.085 to 0.577.
                             The Brooks and Corey characteristic curves can be shown to be a limiting case of
                           van Genuchten (van Genuchten (1978, 1980). For large values of capillary pressure
                                n
                           ((αP c )   1), the following relationships can be derived
                                                         1       n
                                                    P b =   (αP c )   1
                                                         α
                           and

                                                                 n
                                                    λ = mn (αP c )   1
                           Using the Mualem relationship, λ = m/(1−m); for Burdine, λ = 2m/(1−m). These
                           relationships were used for the Brooks and Corey capillary pressure curves presented
                           in Figure 5.3 based on the van Genuchten parameters in Figure 5.1.
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