Page 245 - Geochemical Remote Sensing of The Sub-Surface
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218                                                       T. Ruan and Q. Fei
           SURFACE EXPRESSIONS OF HYDROCARBON MIGRATION


           Gas  anomalies


              According  to  Kartsev  et.  al.  (1959),  Sokolov  (1970),  Horvitz  (1986)  and  Fei  and
           Ruan  (1991),  gas microseepage  associated with petroleum has three  characteristic  styles
           of surface  anomaly:  (1)  apical;  (2)  annular;  and  (3)  linear.  One  or  any  combination  of
           these surface expressions may occur over a given oil or gas field.
              An apical anomaly comprises either a continuous zone of elevated gas concentrations
           or an  area  with  erratic  elevated  gas  concentrations  directly over the  oil  or gas  field.  An
           annular or halo anomaly has the form of a doughnut of continuous or discontinuous high
           gas  concentrations  surrounding  a central  zone  of lower or background  values,  the  latter
           overlying the  surface  projection  of the  oil or gas  field.  In a linear or belt  anomaly,  high
           gas concentrations  are  found continuously or intermittently  along a line  or confined  in a
           belt, usually associated with faults, fracture zones, or matured source beds.
              Both  apical  and  annular  anomalies  can  be  explained  by  diffusion  models  (although
           diffusion  alone  is  unlikely  to  be  responsible  for  them),  whilst  linear  anomalies  are
           readily attributable  to mass flow through an elongated conduit,  such as a fault or fracture
           zone.  Some investigators have argued that diffusion can only lead to the  formation of an
           apical  anomaly  (Price,  1986;  MacElvain,  1969),  but  this  argument  is  only  valid  if
           diffusion  only  takes  place  in  a  homogeneous  medium.  This  is  rarely  the  case  in  the
           natural  environment  and  through  inhomogeneous  media  diffusivity  is  anisotropic  and
           variable  up  to  several  orders  of magnitude.  Indeed  with  certain  combinations  of media,
           annular anomalies can be obtained by diffusion (Ruan et. al.,  1985a,  1985b).
              It  is  vital,  but  not  necessarily  easy,  to  recognise  whether  an  anomaly  is  apical,
           annular  or  linear,  because  the  interpretation  placed  upon  each  of  them  leads  to  quite
           different  courses  of  action.  The  model  used  to  explain  an  apical  anomaly  favours
           drilling  the  anomaly  peak,  whilst  the  model  for  an  annular  anomaly  favours  the  area
           within the  ring of high values.  Follow-up of linear  anomalies  needs  to take  into account
           structural or lithological information.
              All types of anomalies  can be present  over a given oil or gas  field depending  on the
           relative  depth of the field,  its caprock lithology and structural  control,  the gas species  in
           the  microseepage,  their  modes  of  occurrence,  near-surface  lithologies  and  soil  types,
           climate  and  even  the  time  of  year.  This  wide  range  of  factors  renders  gas  anomaly
           interpretation difficult.


           Alteration


              Migrating  hydrocarbons may also  interact with  the rock column  through  which  they
           pass.  These  interactions  become  most  pronounced  as  the  ascending  hydrocarbons
           approach  the  surface  and strive to equilibrate  with  changing  conditions  characterised  by
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