Page 214 - Geochemistry of Oil Field Waters
P. 214

SEDIMENTARY ROCKS                                                     201


            erosion  and  redeposition  of  sediment deposits. The salinity of  the sea may
            change somewhat during transgression but probably not much.
              Deltaic  deposits  result  from a combination of  environmental factors and
            are  related  to  both  fluvial  and  regressive  marine  processes.  During  flood
            times the rivers transport  tremendous volumes. of  material, both clastic and
            organic, into delta areas. Deltaic deposition  is a very important factor in the
            formation  of  petroleum because of  the tremendous amount of  organic ma-
            terial deposited.
              Bathyal-abyssal deposits  are  formed  in  deep-water  areas in  the sea, and
            turbidity currents are responsible  for most of the clastic deposition (Emery,
            1960). Lacustrine deposits are those that are formed in lakes. If  the lake is a
            fresh-water  lake,  the  dissolved  solids  may  be  less  than  1,000  mg/l; in  a
            salt-water lake, the dissolved solids may be greater than 35,000 mg/l.
              Consider a simplistic sedimentation area  where the borderland  area is the
            prime  source  of  sediments.  The  coarse- to fine-grained  clastics  which  are
            weathering  products  of  the  high-mountains borderland  are  deposited  near
            their source.  The clastics are detritus transported  mechanically to the point
            of  sedimentation  and  are  not  solubilized  by  the water  before  deposition.
            Primarily they are the sandstones and shales (clays). They will not be found
            on the for.eland side of  a depositional  basin. Clay deposition  can be detrital
            or  authigenic;  illite  often  is  detrital.  There  are  at  least  two  dozen  clay
            minerals,  many  of  which  occur  in  very  minute  grains and  most  of  which
            cannot  be  resolved  by  high-power  petrographic  microscopes.  The  electron
            microscope,  X-ray  diffraction,  and differential thermal analysis are used to
            determine the type of clay.
              The  clays  are very  important  in  relation  to petroleum  and  gas  because
            they  are the major  component  in the shales from which petroleum  and gas
            are  generated.  The  clays also  possess  base  exchange  properties  which  will
           react  with  constituents  in water and petroleum.  The detrital clays settle in
            low-energy waters and they settle more rapidly from a saline water than from
           a fresh water.

           Depositional environments of the carbonates

              Limestones  and  dolomites  are  the  dominant  carbonate  reservoir  rocks,
            while  the sandstones are the dominant  clastic reservoir rocks (Ham, 1962).
            The carbonates were precipitated  at the place where the rocks first formed,
            while clastics were primarily transported grains.
              Plumley  et  al.  (1962)  classified the  carbonates according to an  energy
           index  of the  water  from  which  they  precipitated.  They divided them into
           five types. Type I is deposited  in quiet water; it consists of calcite, 15-5096
            clay,  and  < 5%  detrital  quartz.  Type  I1  is  deposited  in  intermittently
           agitated water and consists of  calcite, < 25% clay, and < 50% detrital quartz.
           Type I11 is deposited  in slightly agitated water and it consists of calcite with
            up to 50% detrital quartz. Type IV is deposited in moderately agitated water
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