Page 204 - Geotechnical Engineering Soil and Foundation Principles and Practice
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Soil Water
                                                                                             Soil Water  199

                  and highly sensitive weight measurements show a stepwise weight gain as
                  surfaces become covered with discrete layers of molecules. Since the size of the
                  water molecule is known, a simple calculation gives the surface area of the sample.
                  This is the Brunnaer-Emmet-Teller or BET method and is used in the study of
                  clays. Teller later was in charge of development of the hydrogen bomb.

                  Interlayer water is specific to expansive clay minerals, being water that is
                  adsorbed between clay mineral layers. Considerable interlayer water remains
                  in place after oven-drying at 1108C, which is sufficient to remove hygroscopic
                  water. Temperatures in excess of 2008C may be required to remove all interlayer
                  water.

                  Structural OH water is not water until clay minerals are heated sufficiently to
                  break down their crystal structure, normally in the range 500–7008C, depending
                  on the clay mineral.

                  Crystalline water is ice.

                  Evaporated water is part of the soil air, in which the relative humidity may be 100
                  percent. Drying at the ground surface creates a gradient that draws water up from
                  below.


                  10.4 MOVEMENT OF WATER



                  Gravitational water moves only in response to gravity, which is vertically
                  downward in an unsaturated medium because gravity has no horizontal
                  component. As illustrated in Fig. 10.2, when gravitational water encounters a
                  groundwater table that impedes downward seepage, it moves downward laterally
                  toward an outlet that is lower in elevation. If a potential outlet is at the same
                  elevation, gravitational water will not move.

                  Capillary water may move in any direction including horizontal in response to a
                  gradient in capillary pressure, referred to as capillary potential or matric potential.
                  Therefore when a gradient is induced by drying at the ground surface, capillary
                  water is attracted toward the drier zone. Capillary water also moves in response to
                  ground freezing, which by lowering the vapor pressure of water in effect dries a
                  soil out. This movement of capillary water upward into a freezing zone results in
                  the formation of pure ice crystals that cause frost heave, discussed in the next
                  chapter.

                  Hygroscopic and interlayer water move in response to changes in temperature
                  and relative humidity. Freezing therefore can simultaneously cause shrinkage of
                  expansive clay by drawing out interlayer water, and expansion by attracting
                  capillary water that contributes to frost heave.

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