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234                          Geothermal Energy: Renewable Energy and the Environment



                          Table 12.2
                          coefficients of Thermal expansion for Feldspar minerals
                          mineral            α (T )         reference Volume (Å )
                                                −1
                                                                          3
                          Microcline a       1.86e−5             722.02
                          Sanidine b         1.92e−5             723.66
                          Low Albite a       3.07e−5             664.79
                          High Albite c      3.15e−5             666.98
                          a   Hovis and Graeme-Barber 1997
                          b   Hovis et al. 1999
                          c   Stewart and von Limbach 1967



                                        ∆T = 50°      ∆T = 100°


                              0.005

                                                  Sodium
                                                  feldspar
                              0.004             –2,120 cc
                             Fractional volume change  0.003  –1,640 cc  Potassium






                              0.002
                                                                  feldspar

                              0.001                       –1,880 cc
                                            –950 cc

                                0.0
                                 20    40    60    80   100   120  140   160
                                                     ∆T

            FIGUre 12.4  The fractional volume change as a function of temperature for sodium and potassium feld-
            spar. The sodium and potassium feldspar curves are the respective average values for low and high albite, and
            sanidine and microcline from Table 12.2. The negative values in the plot are the change in volume (in cc) that
            would occur for a cubic meter of the pure mineral phases, upon cooling through a ΔT of 50° and 100°.

            common rock forming minerals and their behavior can provide a guide to the response of the rocks
            that make up the bulk of a geothermal reservoir.
              Shown in Figure 12.4 are the fractional changes in volume that occur for sodium and potassium
            feldspars as a function of temperature change. Since the changes for sanidine and microcline are
            very similar, and those for low- and high-albite are very similar, the respective averages for these
            minerals are shown. Also shown in the figure are the number of cubic centimeters by which one
            cubic meter of the pure mineral phases would shrink if it were cooled between 50°C and 100°C.
            Such volume changes, although small, are not insignificant. It is this effect that has been hypoth-
            esized to be the  underlying cause of very small earthquakes in regions where cool water is injected
            into hot geothermal reservoirs.
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