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IMPLICATIONS OF PLATE TECTONICS  413



            deposits in Archean cratons is complicated by the pos-  ments to the effects of rising mantle plumes (Pirajno,
            sibility of unique geologic or tectonic process operating   2004).
            in the early Earth (Section 11.1). These differences   With the development of a narrow ocean basin
            require models that incorporate the unique aspects of   between the rifted continental fragments, new mineral
            Archean geology and tectonics (Herrington  et al.,   deposits are created at the mid-ocean ridge. The present
            1997).                                       day example of this environment is the Red Sea. Here
                                                         13 pools of hot brines (Fig. 13.10) have been located
                                                         along the central ridge where it is intersected by trans-
            13.2.2 Autochthonous and                     form faults. These contain zinc-copper-lead sediments
                                                         of possible economic value, for example the Atlantis II
            allochthonous mineral deposits               Deep, which contains sulfide layers with zinc contents

                                                         of up to 20% which are 20 m thick and cover an area of
                                                                  2
            The various plate tectonic environments in which many   over 50 km . It is generally agreed that the metals are of
            metalliferous deposits are found are shown in Fig. 13.9.   volcanic origin and have been concentrated into brines
            The initial rifting of a continent includes the emplace-  by the thermally induced circulation of seawater
            ment of alkaline and peralkaline igneous rocks and the   through the volcanic rocks and thick evaporite sequences
            establishment of high geothermal gradients (Sections   found in this region (Cowan & Cann, 1988). As the
            7.4.2, 7.2, respectively). Ore minerals are generated   ocean basin evolves, these deposits may become buried
            from this magmatism and from the large-scale circula-  by sediment and reappear in collisional orogens where
            tion of hydrothermal fluids that are energized by it.   the tectonism obscures their original setting. Also asso-

            One group of igneous rocks frequently associated with   ciated with this advanced phase of rifting are sediment-

            extensive mineralization includes carbonatites. These are   hosted massive sulfide deposits which occur in thick
            unusual rocks composed of more than 50% carbonate   continentally derived clastic sediments on passive con-
            minerals that form ring complexes within alkaline   tinental margins. They comprise single or multiple
            rocks. The important elements found in this environ-  lenses of pyrite, galena, and sphalerite ores with minor
            ment are phosphorus (as apatite), niobium (pyrochlore),   silver and copper. These are not common and probably

            rare earths (monazite, bastnaesite), copper, uranium,   reflect the influence of metal-rich-formation waters

            thorium, and zircon. Also found are magnetite, fl uorite,   powered by long-lived geothermal systems.
            barite, strontianite, and vermiculite. Carbonatites may   As an ocean basin continues to grow, contemporane-
            also contribute to the sodium carbonate, chloride, and   ous mineralization takes place at the mid-ocean ridge,

            fluoride found in vast quantities in the lakes of the East   and has been observed at certain locations along the
            African Rift system, although it is possible that these   Pacifi c (Corliss et al., 1979), Atlantic (Scott et al., 1973),
            derive from weathering of the alkaline rocks. Directly   and Indian Ocean ridges. The mineralization is of
            related to the magmatism are porphyry and vein-type   hydrothermal origin and its location depends upon the
            molybdenum deposits associated with subalkaline gran-  availability of oceanic crust of high permeability overly-
            ites, copper-nickel deposits associated with mafi c intru-  ing the magma chamber which allows fl uids to perco-
            sions, and hydrothermal copper deposits. Within the   late with relative ease. Hydrothermal processes of low
            sediments related to rifting, stratiform copper deposits   intensity lead to the formation of ferromanganese
            of great volume are associated with specifi c  shale   nodules, and encrustations of iron and manganese on
            or sandstone horizons. These disseminated ores are   pillow basalts at the layer 1–layer 2 interface. Higher

            believed to form during the first marine transgression   intensity hydrothermal activity has been observed at
            into the continental interior and overlie red-bed hori-  some locations, such as on the East Pacifi c Rise where
            zons, and are probably derived from the copper-rich rift   discharge is of two types. Black smokers are vents where

            basalts in response to the elevated heat flow of the rift.   pyrrhotite particles are discharged, producing ores
            Carbonate hosted lead-zinc-barite ores are also found in   which may be zinc- or iron-rich and containing lesser
            the intracratonic rifts and rifted continental margins   amounts of cobalt, lead, silver, and cadmium. At white

            (Section 7.7), typified by the deposits of the Upper Mis-  smokers little sulfide material is discharged, and the main

            sissippi Valley of North America. Attempts also have   precipitate is barite.
            been made to link a wide range of mineral deposits that   In open ocean conditions ferromanganese nodules
            are related to magmatism in continental rift environ-  and encrustations form on top of basalt or sediments
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