Page 471 - Handbook of Thermal Analysis of Construction Materials
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446 Chapter 10 - Non-Portland Rapid Setting Cements
Two hydration peaks are observed (similar to C S hydration). An
3
initial peak is observed on mixing; peak height is directly related to the
temperature of hydration. An induction period (0.5 hr) was observed at 0.5
hour at 25°C. The minimum rates of heat evolution (at temperatures > 25°C)
increase with temperature. A slower rate of heat evolution, but a larger total
amount of heat released was observed at 25°C. This behavior was attributed
to the retrograde solubility of hydroxyapatite along with incongruent
dissolution of the acidic constituent.
REFERENCES
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Analysis to the Hydration and Conversion Reactions of Calcium Aluminate
Cements, Materiales de Construccion, 42:15–32 (1992)
2. Majumdar, A. J., Edmonds, R. N., and Singh, B., Hydration of Secar 71
Aluminous Cement in the Presence of Granulated Blast Furnace Slag,
Cement Concr. Res., 20:7–14 (1990)
3. Brown, R. A., and Cassel, B., High Alumina Cements: Background and
Application of Thermal Analysis Methods, Am. Lab., 9:45–56 (1977)
4. Midgley, H. G., The Use of Thermal Analysis Methods in Assessing the
Quality of High Alumina Cement Concrete, J. Thermal Analysis, 13:515–
524 (1978)
5. Midgley, H. G., The Mineralogy of Set High Alumina Cement, Trans., Brit.
Ceram. Soc., 66:161–168 (1967)
6. Midgley, H. G., The Mineralogical Examination of Set Portland Cement,
th
4 Int. Symp. Chem. Cement, Paper IV-82, 1:479–490, WA (1960)
7. (a) Midgley, H. G., and Midgley, A., The Conversion of High Alumina
Cement, Mag. Concr. Res., 27:59–77 (1975); (b) Midgley, H., Measurement
of High Alumina Cement-Calcium Carbonate Reactions Using DTA, Clay
Minerals, 19:857–864 (1984)
8. Ramachandran, V. S., and Feldman, R. F., Hydration Characteristics of
Monocalcium Aluminate at a Low Water/Solid Ratio, Cement Concr. Res.,
3:729–750 (1973)
9. Talaber, J., Revay, M., and Wagner, Z., Thermal Analytical Measurements
nd
of Hungarian High-Alumina Cement Concretes, 2 European Symp. on
Thermal Analysis, pp. 498–500, Univ. Aberdeen, Heyden (1981)
10. Das, S. K., Mitra, A., and Das Poddar, P. K., Thermal Analysis of Hydrated
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