Page 471 - Handbook of Thermal Analysis of Construction Materials
P. 471

446               Chapter 10 - Non-Portland Rapid Setting Cements


                                     Two hydration peaks are observed (similar to C S hydration). An
                                                                               3
                              initial peak is observed on mixing; peak height is directly related to the
                              temperature of hydration. An induction period (0.5 hr) was observed at 0.5
                              hour at 25°C. The minimum rates of heat evolution (at temperatures > 25°C)
                              increase with temperature. A slower rate of heat evolution, but a larger total
                              amount of heat released was observed at 25°C. This behavior was attributed
                              to the retrograde solubility of hydroxyapatite along with incongruent
                              dissolution of the acidic constituent.




                              REFERENCES


                                1. Bushnell-Watson, S. M., and Sharp, J. H., The Application of Thermal
                                   Analysis to the Hydration and Conversion Reactions of Calcium Aluminate
                                   Cements, Materiales de Construccion, 42:15–32 (1992)
                                2. Majumdar, A. J., Edmonds, R. N., and Singh, B., Hydration of Secar 71
                                   Aluminous Cement in the Presence of Granulated Blast Furnace Slag,
                                   Cement Concr. Res., 20:7–14 (1990)
                                3. Brown, R. A., and Cassel, B., High Alumina Cements: Background and
                                   Application of Thermal Analysis Methods, Am. Lab., 9:45–56 (1977)
                                4. Midgley, H. G., The Use of Thermal Analysis Methods in Assessing the
                                   Quality of High Alumina Cement Concrete, J. Thermal Analysis, 13:515–
                                   524 (1978)
                                5. Midgley, H. G., The Mineralogy of Set High Alumina Cement, Trans., Brit.
                                   Ceram. Soc., 66:161–168 (1967)
                                6. Midgley, H. G., The Mineralogical Examination of Set Portland Cement,
                                    th
                                   4  Int. Symp. Chem. Cement, Paper IV-82, 1:479–490, WA (1960)
                                7. (a) Midgley, H. G., and Midgley, A., The Conversion of High Alumina
                                   Cement, Mag. Concr. Res., 27:59–77 (1975); (b) Midgley, H., Measurement
                                   of High Alumina Cement-Calcium Carbonate Reactions Using DTA, Clay
                                   Minerals, 19:857–864 (1984)
                                8. Ramachandran, V. S., and Feldman, R. F., Hydration Characteristics of
                                   Monocalcium Aluminate at a Low Water/Solid Ratio, Cement Concr. Res.,
                                   3:729–750 (1973)
                                9. Talaber, J., Revay, M., and Wagner, Z., Thermal Analytical Measurements
                                                                            nd
                                   of Hungarian High-Alumina Cement Concretes, 2  European Symp. on
                                   Thermal Analysis, pp. 498–500, Univ. Aberdeen, Heyden (1981)
                               10. Das, S. K., Mitra, A., and Das Poddar, P. K., Thermal Analysis of Hydrated
                                   Calcium Aluminates, J. Thermal Analysis, 47:765–744 (1996)
   466   467   468   469   470   471   472   473   474   475   476